Polyphenylene Ether Resin Composition for Circuit Boards

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Solution Overview

Problem

Current curable resin compositions for printed circuit boards lack a balance of properties such as high interlaminar bond strength, thermal stability, moisture resistance, dielectric properties, and low thermal expansion, which are essential for reliable electronic applications.

Innovation Solution

A curable composition comprising functionalized poly(phenylene ether) resin, an unsaturated monomer, and a flame retardant like 1,1′(ethane-1,2-diyl)bis[pentabromobenzene], along with a radical initiator and optional fillers and adhesion promoters, to achieve improved thermal stability and reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional curable resin compositions are used for printed circuit boards, then manufacturing simplicity is maintained, but the compositions lack a balanced combination of high interlaminar bond strength, thermal stability, moisture resistance, dielectric properties, and low thermal expansion

Engineering Contradiction:
Improveoverall performance balanceVSAvoidcomposition formulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining poly(phenylene ether) resin with specific flame retardant compounds (such as tetrabromobisphenol or decabromodiphenyl oxide) and fillers to create a resin composition that simultaneously achieves high interlaminar bond strength, thermal stability, moisture resistance, dielectric properties, and low thermal expansion. This multi-component composite approach allows the composition to meet multiple performance requirements that cannot be achieved with a single material.

Inventive Principle:
Principle #40Composite materials

2Temperature

If flame retardant compounds are added to improve thermal stability and fire resistance, then thermal stability is improved, but the composition may exhibit increased thermal expansion or reduced dielectric properties

Engineering Contradiction:
Improvethermal stabilityVSAvoidthermal expansion and dielectric property degradation
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by carefully controlling the concentration and type of flame retardant compounds used in the resin composition. By optimizing the amount of flame retardant (typically 5-50 parts by weight per 100 parts of resin) and selecting specific compounds with appropriate molecular structures, the composition achieves high thermal stability while minimizing negative impacts on thermal expansion and dielectric properties. The use of functionalized poly(phenylene ether) with specific molecular weight and structure also plays a crucial role in maintaining dielectric performance.

Inventive Principle:
Principle #35Parameter changes

3Strength

If high interlaminar bond strength is achieved through optimized resin composition, then bonding performance is improved, but the formulation complexity increases

Engineering Contradiction:
Improveinterlaminar bond strengthVSAvoidformulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies local quality by using functionalized poly(phenylene ether) resin with specific molecular structures (containing hydroxyl groups at specific positions and controlled molecular weight) that are particularly effective at forming strong bonds between laminate layers. The resin composition is designed with specific local chemical characteristics that promote strong interlaminar bonding while maintaining other desired properties. This targeted approach to molecular structure optimization achieves high bond strength without requiring overly complex formulations.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits high interlaminar bond strength, robust thermal stability, excellent dielectric properties, very low thermal expansion, and high reliability, making it suitable for single and multilayer printed circuit boards.

Implementation Method 1

a curable composition comprising: a functionalized poly(phenylene ether) having the structure: [structure shown] a radical initiator; an unsaturated monomer; and a flame retardant

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS9051465B1Thermosetting resin composition containing a polyphenylene ether and a brominated fire retardant compound
Publication Date: 2015.06.09 NELTEC INC
  • US9051465B1 patent drawing
  • US9051465B1 patent drawing
  • US9051465B1 patent drawing

AI summary

A resin composition for use in making pre-pregs and structural laminates contains a curable composition comprising:a functionalized poly(phenylene ether) having the structure:a radical initiator;an unsaturated monomer; anda flame retardant comprising the compound 1,1′(ethane-1,2-diyl)bis[pentabromobenzene],wherein Y, m and n are defined herein.