Polysaccharide Filament Ductility via Thermal Processing

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Solution Overview

Problem

Polysaccharide filaments, such as starch-based materials, exhibit brittle properties and lack ductility, making them unsuitable for applications requiring flexibility and strength, like toilet tissue or paper towels, due to their inherent structure and the need for plasticizers or synthetic polymers which are costly or undesirable.

Innovation Solution

Processing polysaccharide filaments at elevated temperatures between 170°C to 175°C for 1 to 2 minutes to create a more homogeneous melt composition, then quickly quenching them, results in filaments with improved ductility and birefringence without the need for plasticizers or synthetic polymers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If plasticizers are added to polysaccharide filaments to improve ductility, then flexibility and stretchability are enhanced, but wet tensile strength deteriorates

Engineering Contradiction:
ImproveductilityVSAvoidwet tensile strength
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent removes plasticizers from the polysaccharide filament composition entirely, achieving ductility through alternative means (high-amylose starch formulation and processing conditions) rather than through plasticizer addition, thus eliminating the wet strength deterioration problem

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters by using high-amylose starch (≥70% amylose content) and controls processing parameters (temperature, moisture content) to achieve ductile properties without plasticizers, resolving the contradiction between ductility and wet strength

Inventive Principle:
Principle #35Parameter changes

2Strength

If synthetic polymers are added to polysaccharide filaments to improve mechanical properties, then ductility and strength are enhanced, but manufacturing cost increases

Engineering Contradiction:
Improvemechanical propertiesVSAvoidmanufacturing cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent eliminates synthetic polymer additives from the composition, achieving the desired mechanical properties through optimized polysaccharide formulation (high-amylose starch) and processing conditions, thereby removing the cost burden of expensive synthetic additives

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a homogeneous polysaccharide-based composition (high-amylose starch with controlled moisture and plastic content) throughout the filament, avoiding the need for synthetic polymer blends, which simplifies manufacturing and reduces costs

Inventive Principle:
Principle #33Homogeneity

3Stability of the object's composition

If polysaccharide filaments are processed at elevated temperatures to improve homogeneity, then material uniformity is enhanced, but energy consumption increases

Engineering Contradiction:
ImprovehomogeneityVSAvoidenergy consumption
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by moving object

Solution Approach 1:

The patent optimizes the processing temperature parameter to a specific range (143-155°C) that achieves sufficient homogeneity and ductility while minimizing energy consumption, avoiding excessive heating that would waste energy

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces polysaccharide filaments with an Elongation at Rupture greater than 100% and significant birefringence, enhancing their flexibility and strength, making them suitable for sanitary tissue products without the use of costly additives.

Implementation Method 1

polysaccharide filaments that exhibit birefringence

Methodology Applied
Scientific EffectBirefringence: Birefringence

Implementation Method 2

Processing polysaccharide filaments at elevated temperatures between 170°C to 175°C

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

quickly quenching them

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS11118031B2Fibrous structures comprising polysaccharide filaments
Publication Date: 2021.09.14 PROCTER & GAMBLE CO
  • US11118031B2 patent drawing
  • US11118031B2 patent drawing
  • US11118031B2 patent drawing

AI summary

Polysaccharide filaments and fibrous structures containing such polysaccharide filaments and more particularly polysaccharide filaments that exhibit birefringence are provided.