Polysaccharide Wax Modifier for Hydrocarbon Fluid Deposition

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Solution Overview

Problem

Hydrocarbon production from subterranean formations faces challenges due to the precipitation and deposition of solids like waxes, asphaltenes, and other insoluble materials during changes in pressure and temperature, leading to operational issues such as blockages and reduced production rates in pipelines and storage tanks.

Innovation Solution

The use of wax modifiers derived from polysaccharides reacted with fatty acid reagents, which are added to hydrocarbon fluids to inhibit the precipitation and deposition of waxes and other insoluble materials by altering their crystal morphology and intermolecular interactions, thereby reducing aggregation and deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If chemical additives are used to disrupt solid particle growth and inhibit precipitate formation, then solid deposition is mitigated, but fluid composition complexity increases

Engineering Contradiction:
Improvesolid depositionVSAvoidfluid composition
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent uses chemical additives as intermediary substances that mediate between the hydrocarbon fluid and solid particles. These additives adsorb onto particle surfaces, modifying interfacial properties and preventing direct interaction between particles and equipment surfaces, thereby mitigating deposition while maintaining fluid integrity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention employs composite chemical formulations containing multiple functional components including surfactants, polymers, and inhibitors work synergistically. This composite approach provides multifunctional protection against various deposition mechanisms while optimizing performance at lower overall concentrations

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If dispersants and solvents are added to alter particle size and shape, then deposition is reduced, but fluid viscosity increases

Engineering Contradiction:
ImprovedepositionVSAvoidfluid viscosity
Core Design Contradiction:
Object-affected harmful factorsVSUse of energy by moving object

Solution Approach 1:

The patent utilizes additives that induce parameter changes in particle characteristics, specifically altering particle size distribution and morphological shape factors. By controlling these parameters, the additives prevent particle aggregation and deposition while minimizing impact on bulk fluid viscosity through optimized molecular structure and concentration

Inventive Principle:
Principle #35Parameter changes

3Ease of repair

If chemical additives are used to disperse deposited solids, then scale and wax buildup is remediated, but operational complexity increases

Engineering Contradiction:
Improvescale and wax remediationVSAvoidoperational procedure
Core Design Contradiction:
Ease of repairVSDevice complexity

Solution Approach 1:

The patent implements self-service functionality through chemical additives that automatically disperse and remove deposited solids without requiring mechanical intervention. The additives continuously circulate with the fluid stream, autonomously detecting and acting on deposited materials through adsorption and detachment mechanisms, eliminating the need for separate remediation operations

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The wax modifiers effectively delay or prevent the precipitation of waxes and other insoluble components, reducing deposition and maintaining fluid flow, thereby enhancing production efficiency and reducing operational costs by stabilizing poorly soluble components and dispersing existing aggregates.

Implementation Method 1

chemical additives may operate by disrupting the growth of solid particles or other crystalline materials, leading to a decrease in the average size of these insoluble impurities and inhibiting precipitate formation

Methodology Applied
Scientific EffectCrystal morphology alteration: Crystallisation

Implementation Method 2

chemical additives may operate by disrupting the growth of solid particles or other crystalline materials, leading to a decrease in the average size of these insoluble impurities

Methodology Applied
Scientific EffectCrystallization disruption: Crystallisation

Implementation Method 3

chemical additives may also disperse deposited solids and remediate scale and wax buildup

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS10647906B2Wax modifier in hydrocarbon fluid and method of using the same
Publication Date: 2020.05.12 M I LLC(US)
  • US10647906B2 patent drawing
  • US10647906B2 patent drawing
  • US10647906B2 patent drawing

AI summary

Compositions may include a wax modifier that is the product of a reaction between a polysaccharide having a number of sugar subunits in the range of 2 to 60 and one or more fatty acid reagents, and a reservoir fluid produced from a subterranean formation comprising one or more components capable of producing waxes. Methods may include contacting a hydrocarbon fluid with a wax modifier, wherein the wax modifier is the product of the reaction of a polysaccharide and one or more fatty acid reagents. Methods may also include introducing a wax modifier into a wellbore penetrating a subterranean formation, wherein the wax modifier is the product of a reaction between a polysaccharide and one or more fatty acid reagents; producing hydrocarbons from the subterranean formation; and allowing the wax modifier to inhibit the precipitation of a wax.