Polysilicon Reactor Gas Nozzle Height for Uniform Deposition

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Solution Overview

Problem

The Siemens method for producing polycrystalline silicon often results in undesirable morphology due to uneven gas supply, leading to quality deterioration and lower yield, as the raw material gas can cause temperature variations and stagnation on the silicon seed rods, affecting deposition rates and surface irregularities.

Innovation Solution

A reactor design with tapered cylindrical raw material gas supply nozzles extending from the bottom of the reactor, allowing for uniform gas distribution across the silicon seed rods by adjusting the nozzle height between -10 cm to +5 cm relative to the electrode, ensuring consistent gas supply from top to bottom and preventing popcorn-like irregularities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If raw material gas is supplied from the bottom of the reactor directly toward the lower part of the column-shaped polycrystalline silicon, then gas supply is achieved, but the temperature of the lower part decreases and the deposition speed is reduced, causing undesirable morphology

Engineering Contradiction:
Improveraw material gas supplyVSAvoidtemperature of lower part
Core Design Contradiction:
Quantity of substanceVSTemperature

Solution Approach 1:

The gas supply system is segmented into multiple nozzles distributed at different heights rather than a single bottom supply point. This segmentation allows gas to be supplied uniformly across different zones of the silicon seed rod, preventing localized temperature decreases and maintaining consistent deposition rates throughout the crystal growth process.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The gas supply is transitioned from a one-dimensional bottom-up approach to a three-dimensional distributed supply system. By positioning nozzles at multiple height levels (from -10 cm to +5 cm relative to the electrode), gas is supplied uniformly across the entire surface area of the silicon seed rod, eliminating the temperature gradient problem associated with direct bottom supply.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Quantity of substance

If raw material gas is supplied from the bottom of the reactor, then gas reaches the silicon seed rod, but gas stagnates at the upper part and popcorn-like irregularities develop on the surface

Engineering Contradiction:
Improveraw material gas supplyVSAvoidsurface morphology
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The gas supply system is divided into multiple nozzles positioned at different heights, creating segmented gas delivery zones. This prevents gas stagnation by ensuring continuous flow across all regions of the silicon seed rod, and eliminates popcorn-like irregularities by maintaining uniform deposition conditions throughout the crystal growth process.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The nozzle height positioning (-10 cm to +5 cm relative to the electrode) is optimized based on observed deposition patterns and gas flow characteristics. This feedback-driven positioning ensures that gas is supplied at the precise locations and heights needed to prevent stagnation and maintain surface quality, allowing the system to self-correct gas distribution issues.

Inventive Principle:
Principle #23Feedback

3Productivity

If many silicon seed rods are installed in the reactor, then production capacity is increased, but uniform gas supply to all seed rods becomes difficult

Engineering Contradiction:
Improveproduction capacityVSAvoiduniformity of deposition
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The gas supply system is segmented into multiple nozzles distributed throughout the reactor volume, with each nozzle serving a specific zone. This segmentation allows independent optimization of gas flow to each silicon seed rod, ensuring uniform deposition even when many seed rods are installed simultaneously and maintaining consistent crystal quality across all products.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The distributed nozzle system provides universal gas supply capability across all silicon seed rods regardless of their specific positions. The multi-level nozzle arrangement (-10 cm to +5 cm height range) creates a universal gas distribution field that can simultaneously serve multiple seed rods uniformly, enabling high productivity without compromising deposition uniformity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design stabilizes the gas supply, preventing undesirable morphology and enhancing the quality of polycrystalline silicon production by maintaining uniform deposition rates across the seed rods, thus improving yield and surface smoothness.

Implementation Method 1

electricity is supplied through the electrode located on both ends to a whole part of the silicon seed rod, thereby heating the silicon seed rod in its entirety by Joule heat thereof to a temperature at which the raw material gas is thermally decomposed

Methodology Applied
Scientific EffectJoule heat: Joule Heating

Implementation Method 2

The raw material gas supplied into the reactor is in contact with the surface of the heated silicon seed rod to cause thermal decomposition or hydrogen reduction

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 3

The raw material gas supplied into the reactor is in contact with the surface of the heated silicon seed rod to cause thermal decomposition or hydrogen reduction, thereby Polycrystalline silicon is deposited on the surface of the silicon seed rod

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Data Source

PatentEP2039653B1Reactor for polycrystalline silicon and polycrystalline silicon production method
Publication Date: 2015.12.23 MITSUBISHI MATERIALS CORP
  • EP2039653B1 patent drawingFigure 1
  • EP2039653B1 patent drawingFigure 2
  • EP2039653B1 patent drawingFigure 3

AI summary

The reactor for polycrystalline silicon (1) is a reactor for polycrystalline silicon in which a silicon seed rod (4) installed inside the reactor is heated by supplying electricity, a raw material gas supplied inside the reactor is allowed to react, thereby producing polycrystalline silicon on the surface of the silicon seed rod (4), and specifically, the reactor for polycrystalline silicon is provided with a raw material gas supply port (6) installed on the bottom (2) of the reactor and a raw material gas supply nozzle attached to the raw material gas supply port (6) so as to be communicatively connected and extending upward, in which the upper end of the raw material gas supply nozzle is set to a height in a range from -10 cm to +5 cm on the basis of the upper end of the electrode (5) which retains the silicon seed rod.