Polysiloxane Polyurethane Composite Coating for Ice Adhesion

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Solution Overview

Problem

Wind turbine blades and aircraft parts face inefficiencies due to ice build-up, which increases weight and reduces operational efficiency, as existing methods fail to effectively mitigate ice accumulation under extreme weather conditions.

Innovation Solution

A method involving the application of a curable film-forming composition comprising a polysiloxane polymer and a silane curing agent, followed by a second composition with isocyanate functional groups, to create a coating that reduces ice adhesion and maintains structural integrity under ice-forming conditions, demonstrated by a maximum average load force of 400 N in ice adhesion tests.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a coating is applied to mitigate ice build-up, then ice adhesion is reduced, but the coating may compromise structural integrity or durability

Engineering Contradiction:
Improveice adhesionVSAvoidstructural integrity
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent applies a multi-layer composite coating system where a polysiloxane polymer coating is applied first to provide icephobic properties, followed by a polyurethane topcoat to enhance durability and structural integrity. This composite structure combines the ice-mitigating properties of polysiloxane with the protective qualities of polyurethane, resolving the contradiction between reducing ice adhesion and maintaining strength.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If a flexible coating with lower Young's modulus is used to reduce ice adhesion, then ice build-up is mitigated, but the coating may be less durable

Engineering Contradiction:
Improveice build-up mitigationVSAvoidcoating durability
Core Design Contradiction:
Object-affected harmful factorsVSDuration of action of stationary object

Solution Approach 1:

The patent creates a composite coating system where the flexible polysiloxane base coat provides icephobicity while the more durable polyurethane topcoat protects against environmental degradation. The layered structure allows each material to perform its optimal function, extending the service life of the coating system while maintaining ice-mitigating properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes the flexible polysiloxane polymer coating as a thin film that can deform under ice loading, preventing ice adhesion through elastic deformation. This flexible base layer is then protected by a more rigid topcoat, combining the benefits of flexibility for ice mitigation with protection for durability.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating effectively mitigates ice build-up on substrates, ensuring efficient operation by reducing ice adhesion and maintaining structural integrity, thus enhancing the performance of wind turbine blades and aircraft parts in extreme weather.

Implementation Method 1

a polysiloxane polymer comprising hydroxyl functional groups and a silane curing agent comprising at least two alkoxy and/or acyloxy functional groups

Methodology Applied
Scientific EffectSilane curing: Chemical Bonding

Implementation Method 2

a curing agent comprising isocyanate functional groups; at least one film-forming polymer comprising functional groups reactive with the isocyanate groups

Methodology Applied
Scientific EffectIsocyanate reaction: Chemical Bonding

Implementation Method 3

a polysiloxane present in the second curable film-forming composition in an amount sufficient to mitigate ice build-up on the substrate

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Data Source

PatentEP2785801B2Method of mitigating ice build-up on a substrate
Publication Date: 2019.07.03 PPG INDUSTRIES OHIO INC
  • EP2785801B2 patent drawing
  • EP2785801B2 patent drawing
  • EP2785801B2 patent drawing

AI summary

The present invention is directed to a method of mitigating ice build-up on a substrate, comprising applying to the substrate combinations of curable film-forming compositions. The curable film-forming compositions may comprise functional film-forming polymers and curing agents or any of various polysiloxanes and optionally silanes with reactive groups. The film-forming compositions can be applied directly to the surface of the substrate or to a primer coat on the substrate.