Polysiloxane Surfactant Ink for Impermeable Media Fixability

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Solution Overview

Problem

Existing aqueous inks have insufficient fixability and high-speed printing ability on impermeable print media, and do not meet the durability requirements for outdoor applications, with surfactant choice being a critical but inadequately addressed factor.

Innovation Solution

An ink formulation incorporating a polysiloxane surfactant with an HLB value of 8 or less and acryl-silicone resin particles, which improves fixability, adhesiveness, and storage stability by enhancing the ink's affinity to impermeable print media and preventing phase separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water-based ink is used for printing on impermeable print media, then environmental safety is improved, but fixability and adhesiveness deteriorate

Engineering Contradiction:
Improveenvironmental safetyVSAvoidfixability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the water-based ink by selecting specific surfactants with HLB values of 3-7 and using acrylic resin emulsions with specific glass transition temperatures (-50°C to 0°C). These parameter changes enable the ink to achieve both environmental safety and improved fixability on impermeable media.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink formulation combining water, specific surfactants (polysiloxane, fluorinated, or polyglycerin-based), and acrylic resin emulsions with controlled glass transition temperatures. This composite approach allows the ink to exhibit both environmental compatibility and enhanced adhesion to plastic films and other impermeable substrates.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional surfactants are used in water-based ink, then ink formulation simplicity is maintained, but phase separation occurs during storage

Engineering Contradiction:
Improveink formulation simplicityVSAvoidstorage stability
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The patent specifies precise parameter ranges for surfactant HLB values (3-7) and glass transition temperatures (-50°C to 0°C), along with controlled resin solid content (10-40%). These parameter constraints prevent phase separation while maintaining formulation simplicity and manufacturing feasibility.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies the concept of local quality by selecting surfactants and resins with specific localized properties (HLB values, glass transition temperatures) that are optimized for different aspects of ink performance. This ensures stability during storage while maintaining printability and fixability.

Inventive Principle:
Principle #3Local quality

3Productivity

If high-speed printing is performed with water-based ink, then productivity is improved, but bead formation increases

Engineering Contradiction:
Improveprinting speedVSAvoidimage quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent optimizes surface tension parameters through careful selection of surfactants with specific HLB values, and controls viscosity parameters through resin selection with appropriate glass transition temperatures. These parameter optimizations prevent bead formation during high-speed printing while maintaining productivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink achieves improved fixability, adhesiveness, and storage stability, preventing bead formation and transfer during high-speed printing, while maintaining image quality and durability suitable for outdoor applications.

Implementation Method 1

a polysiloxane surfactant, which has an HLB value of 8 or less

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Implementation Method 2

enhancing the ink's affinity to impermeable print media

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 3

acryl-silicone resin particles... preventing phase separation

Methodology Applied
Scientific EffectDispersion stabilization: Dispersion (of waves)

Implementation Method 4

improves fixability, adhesiveness... by enhancing the ink's affinity to impermeable print media

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10119042B2Ink, inkjet printing apparatus, inkjet printing method, and printed matter
Publication Date: 2018.11.06 RICOH CO LTD
  • US10119042B2 patent drawing
  • US10119042B2 patent drawing
  • US10119042B2 patent drawing

AI summary

An ink including: water; at least one organic solvent; a polysiloxane surfactant; and acryl-silicone resin particles, where the polysiloxane surfactant has an HLB value of 8 or less.