Polysuccinimide Microcapsule Shell Stability in Surfactant Bases

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Solution Overview

Problem

The perfumery industry faces challenges in maintaining the olfactory benefit of odoriferous compounds due to their volatility, particularly 'top-notes,' which require stable delivery systems that can survive in aggressive surfactant-containing consumer product bases without degrading.

Innovation Solution

A process for preparing core-shell microcapsules by reacting a polyfunctional monomer with a polysuccinimide derivative during interfacial polymerization, forming a stable oil-in-water emulsion that encapsulates hydrophobic materials like perfumes, ensuring effective deposition and longevity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of moving object

If polyurea and polyurethane-based microcapsules are used, then long-lasting olfactory effect is achieved, but stability in aggressive surfactant-containing bases deteriorates

Engineering Contradiction:
Improveolfactory effect durationVSAvoidstability in consumer product base
Core Design Contradiction:
Duration of action of moving objectVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the shell material by using polysuccinimide derivatives with specific functional groups (carboxylic acid, hydroxyl, or amine groups) instead of conventional polyurea/polyurethane compositions. This parameter change enables the shell to resist degradation by aggressive surfactants while maintaining encapsulation functionality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite shell structure by reacting polysuccinimide derivatives with polyfunctional monomers to form a cross-linked network. This composite material combines the benefits of polysuccinimide's stability in aggressive media with the encapsulation properties of traditional microcapsule materials.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If conventional microcapsule delivery systems are used, then perfume encapsulation is achieved, but deposition performance in challenging bases deteriorates

Engineering Contradiction:
Improveperfume encapsulationVSAvoiddeposition performance
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent modifies the shell's chemical parameters by incorporating polysuccinimide derivatives with specific functional groups that enhance adhesion to substrates. The carboxylic acid, hydroxyl, or amine groups provide improved deposition characteristics on various surfaces while maintaining perfume encapsulation capacity.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If microcapsules are exposed to aggressive surfactant detergents, then consumer product functionality is achieved, but microcapsule physical dissociation increases

Engineering Contradiction:
Improvecompatibility with consumer productsVSAvoidmicrocapsule integrity
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent converts the harmful effect of aggressive surfactants into a beneficial interaction by designing a shell with polysuccinimide derivatives that are specifically resistant to surfactant degradation. The shell's chemical structure is engineered to withstand or even interact favorably with surfactant environments, transforming the challenging condition into a compatible system.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process yields microcapsules with improved stability and deposition performance, maintaining the olfactory benefit of perfumes in challenging consumer product bases, such as detergents, while ensuring long-lasting fragrance release.

Implementation Method 1

performing a curing step to form core-shell microcapsules in the form of a slurry

Methodology Applied
Scientific EffectInterfacial polymerization: Chemical Bonding

Implementation Method 2

dispersing the oil phase obtained in step a) into an aqueous solution comprising a polysuccinimide derivative to form an oil-in-water emulsion

Methodology Applied
Scientific EffectEmulsion: Emulsion

Data Source

PatentUS11666881B2Process for preparing polysuccinimide derivatives-based microcapsules
Publication Date: 2023.06.06 FIRMENICH SA
  • US11666881B2 patent drawing
  • US11666881B2 patent drawing
  • US11666881B2 patent drawing

AI summary

Described herein is a new process for the preparation of polysuccinimide derivatives-based core-shell microcapsules. Also described are microcapsules, as well as perfuming compositions and consumer products including these microcapsules, in particular perfumed consumer products in the form of home care or personal care products.