Polysulfone Amide Photoresist for Low-Temperature Water-Based Development
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Conventional heat-resistant photoresists require high-temperature cyclization reactions, leading to thermal distortion in thin wafers and environmental concerns due to organic solvent developers, while alternatives lack alkali solubility for water-based development.
Innovation Solution
A polysulfone amide compound with specific repeating units and a resin composition that allows pattern formation without high-temperature cyclization, using a water-based developer and incorporating a crosslinking agent and acid generator for improved solubility and development.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If polyimide or polybenzoxazole are used as heat resistant photoresist materials, then heat resistance and stable pattern shape are improved, but high-temperature treatment (300°C or higher) is required causing thermal distortion in thin wafers
Solution Approach 1:
The patent changes the chemical structure parameters by introducing polysulfone amide compounds with specific repeating units containing sulfur atoms and aromatic residues. This structural modification enables the material to achieve heat resistance without requiring high-temperature cyclization, allowing pattern formation at lower temperatures that prevent wafer thermal distortion.
Solution Approach 2:
The patent creates a composite resin composition by combining polysulfone amide compound with other components including crosslinking agents and solvents. This composite approach achieves both heat resistance and alkali solubility, resolving the contradiction between thermal stability and development compatibility.
2Temperature
If PEES (polyether ether sulfone) is used as negative type photosensitive polymer, then high-temperature treatment is not required, but alkali solubility is lost causing difficulty in development using water-based developer
Solution Approach 1:
The patent modifies the chemical parameters by incorporating amide groups and specific aromatic residues into the polysulfone backbone. This creates a structure that maintains thermal stability while introducing alkali solubility through the amide functional groups, enabling water-based development.
Solution Approach 2:
The patent uses a water-based developer as an intermediary medium that can effectively remove unexposed portions of the resist. The polysulfone amide compound is specifically designed to be soluble in this aqueous alkali solution, facilitating easy and environmentally friendly development without requiring organic solvents.
3Ease of operation
If organic solvent developer is used for PEES, then development is possible, but environmental load and waste liquid treatment become problematic
Solution Approach 1:
The patent adopts a water-based developer system that is environmentally benign and economically viable. The aqueous alkali solution can be easily disposed of or treated, eliminating the need for expensive and environmentally hazardous organic solvent recovery systems.
Solution Approach 2:
The patent converts the potential harm of lacking alkali solubility into a benefit by deliberately designing the polysulfone amide structure to include alkali-soluble functional groups. This enables the use of water-based developers, transforming an environmental burden into an environmental advantage.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The polysulfone amide compound enables pattern formation with excellent resolution and physical properties using a water-based developer, reducing environmental impact and avoiding high-temperature treatments.
Implementation Method 1
an acid generator for generating an acid by photolysis
Data Source
AI summary
Disclosed are a polysulfone amide compound having a repeating unit represented by formula (1) (in formula (1), R1-R8 each independently represent a hydrogen atom or a monovalent organic group, X represents a divalent linking group which is not conjugated with a benzene ring to be linked thereto, and Y represents a divalent aromatic residue), and a resin composition comprising the polysulfone amide compound.


