Polythiourethane Molded Product SH Group Concentration

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Solution Overview

Problem

Existing methods for producing molded products with excellent impact resistance and dyeability are limited by the specific combination of monomers used, and there is a need for a method that achieves these characteristics regardless of the monomer combination.

Innovation Solution

A molded product with a specific range of SH group concentration (0.30 wt % to 3.0 wt %) is developed, using a polymerizable composition comprising a polyisocyanate compound and a polythiol compound, which results in excellent impact resistance and dyeability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If specific compounds are combined to achieve excellent impact resistance and dyeability, then these characteristics are improved, but the method is limited by specific monomer combinations and lacks universality

Engineering Contradiction:
Improveimpact resistanceVSAvoidmonomer combination flexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The invention changes the parameter of SH group concentration to a specific range (0.05-5.0 wt%) to achieve excellent impact resistance and dyeability. This parameter-based approach allows universality across different monomer combinations while maintaining reliable performance, resolving the contradiction between reliability and adaptability.

Inventive Principle:
Principle #35Parameter changes

2Weight of moving object

If polythiourethane is used as a material for plastic lenses, then light weight and high refractive index are achieved, but control over impact resistance and dyeability becomes difficult

Engineering Contradiction:
Improvelens weightVSAvoidimpact resistance
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The invention introduces SH group concentration (0.05-5.0 wt%) as a controlling parameter to achieve excellent impact resistance in polythiourethane-based plastic lenses. This allows maintaining the light weight advantage while gaining reliable impact resistance through parameter optimization rather than being constrained by material selection alone.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The molded product achieves excellent releasability, impact resistance, and dyeability, making it suitable for use in optical materials and plastic lenses.

Implementation Method 1

a molded product including a polythiourethane, in which an SH group concentration according to an IR analysis method is 0.30 wt % to 3.0 wt %

Methodology Applied
Scientific EffectPolymerization reaction: Chemical Bonding

Implementation Method 2

an SH group concentration according to an IR analysis method

Methodology Applied
Scientific EffectIR analysis: Absorption Spectroscopy

Data Source

PatentUS12234315B2Molded product and uses thereof
Publication Date: 2025.02.25 MITSUI CHEMICALS INC
  • US12234315B2 patent drawing
  • US12234315B2 patent drawing

AI summary

A molded product of the present invention includes a polythiourethane, in which an SH group concentration according to an IR analysis method is 0.30 wt % to 3.0 wt %.