Polyurea Microcapsules for Stable Piroctone Scalp Deposition

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Solution Overview

Problem

Existing encapsulation methods for piroctone compounds are unstable, leading to reduced performance and inefficient deposition on the scalp, and there is a need for a stable system to enhance antidandruff efficacy.

Innovation Solution

A core shell microcapsule with a liquid core containing piroctone compound and a polyurea shell formed from aliphatic isocyanates and amines, using a Pickering emulsion-type process, with a deposition aid on the shell for enhanced adherence to the scalp and hair.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If encapsulation methods are used to aid deposition and increase effectiveness of antidandruff agents, then deposition efficiency is improved, but stability of the encapsulated system deteriorates

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidsystem stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the shell material by specifying polyurea formed from monomeric units of aliphatic isocyanates and amines, and controls the core-to-shell ratio and particle size distribution to achieve both stable encapsulation and effective deposition of piroctone compounds

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material structure with a liquid core containing piroctone compound and solvent, surrounded by a polyurea shell formed from aliphatic isocyanates and amines, creating a stable encapsulated system that maintains both deposition efficiency and system stability

Inventive Principle:
Principle #40Composite materials

2Reliability

If encapsulation is used to enhance antidandruff effectiveness, then treatment efficacy is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveantidandruff effectivenessVSAvoidencapsulation structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent simplifies the encapsulation structure by defining specific parameter ranges for particle size (0.1-10 μm with Dv0.5 of 0.3-5 μm) and core-to-shell ratio (9:1 to 1:1), enabling effective antidandruff treatment while maintaining manufacturable complexity levels

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The microcapsules provide stable and uniform distribution, allowing for effective deposition and retention of piroctone on the scalp, enhancing antidandruff performance in hair care compositions.

Implementation Method 1

the liquid core comprises solvent and a piroctone compound

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

the shell comprises polyurea formed from monomeric units of aliphatic isocyanates and amines

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

with a deposition aid on the shell for enhanced adherence to the scalp and hair

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS12496565B2Microcapsule and hair care composition
Publication Date: 2025.12.16 CONOPCO INC

AI summary

A core shell microcapsule having a liquid core and an outer shell, in which the liquid core comprises solvent and a piroctone compound and the shell comprises polyurea formed from monomeric units of aliphatic isocyanates and amines.