Polyurethane Binder Dispersion for Inkjet Abrasion Resistance

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Solution Overview

Problem

Inkjet printing technologies face challenges in achieving adequate abrasion resistance and mechability of printed images due to the reduction of polyurethane binder content below 1 wt%, leading to poor durability and damage from media rollers.

Innovation Solution

A polyurethane-based binder dispersion is developed, comprising water and specific components such as polyisocyanate, polyols, carboxylic acid functional groups, and sulfonic/sulfonate compounds, which improves the dispersion's stability and interaction with ink vehicles, enhancing the abrasion resistance and mechability of printed images.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If polyurethane binder content is reduced below 1 wt% to improve mechability, then the inkjet printability is improved, but abrasion resistance deteriorates

Engineering Contradiction:
ImprovemechabilityVSAvoidabrasion resistance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the polyurethane binder by incorporating specific components: polyisocyanate (20-45 wt%), polyols (10-70 wt%), carboxylic acid functional groups (1-10 wt%), and sulfonic/sulfonate compounds (1-20 wt%). This parameter modification allows the binder to achieve both low viscosity for good mechability and high crosslinking density for improved abrasion resistance, resolving the contradiction between printability and durability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite polyurethane binder system combining multiple components: polyisocyanate, polyols, carboxylic acid functional groups, and sulfonic/sulfonate compounds. This composite approach enables synergistic effects where the polyisocyanate provides crosslinking, the polyols provide flexibility, the carboxylic acid groups enhance adhesion, and the sulfonic groups improve dispersibility and durability, achieving both mechability and abrasion resistance simultaneously.

Inventive Principle:
Principle #40Composite materials

2Reliability

If polyurethane binder content is increased to improve abrasion resistance, then durability is improved, but mechability deteriorates

Engineering Contradiction:
Improveabrasion resistanceVSAvoidmechability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent optimizes the concentration parameters of individual components within the polyurethane binder system. By controlling polyisocyanate at 20-45 wt%, polyols at 10-70 wt%, carboxylic acid functional groups at 1-10 wt%, and sulfonic/sulfonate compounds at 1-20 wt%, the formulation achieves the right balance between crosslinking density for durability and molecular flexibility for mechability, allowing the binder to withstand both abrasion and media roller stress.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite polyurethane binder combines materials with complementary properties: polyisocyanate for crosslinking and durability, polyols for flexibility and mechability, carboxylic acid functional groups for adhesion, and sulfonic/sulfonate compounds for dispersibility. This composite structure creates a binder that simultaneously provides abrasion resistance and mechability by leveraging the strengths of each component.

Inventive Principle:
Principle #40Composite materials

3Reliability

If polyurethane binder content is increased to improve abrasion resistance, then durability is improved, but printed image quality deteriorates

Engineering Contradiction:
Improveabrasion resistanceVSAvoidprinted image quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent modifies the chemical composition parameters of the polyurethane binder by incorporating specific functional groups and compounds at optimized concentrations. The carboxylic acid functional groups (1-10 wt%) and sulfonic/sulfonate compounds (1-20 wt%) enhance the binder's interaction with ink vehicles and media, improving image quality while the polyisocyanate (20-45 wt%) and polyols (10-70 wt%) provide the necessary crosslinking for durability, thus resolving the contradiction between durability and image quality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite polyurethane binder system integrates multiple functional components that work synergistically: polyisocyanate for crosslinking and durability, polyols for flexibility, carboxylic acid functional groups for adhesion to media, and sulfonic/sulfonate compounds for dispersibility and ink vehicle interaction. This composite structure enables the binder to maintain printed image quality while providing enhanced abrasion resistance through the combined effects of all components.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyurethane-based binder dispersion significantly improves the abrasion resistance and mechability of inkjet ink compositions, allowing printed images to withstand stress from media rollers and maintain optical density and gloss, even when rubbed against hot rollers.

Implementation Method 1

The polyurethane can comprise: (A) a polyisocyanate; (B) a first polyol having a chain with two hydroxyl functional groups at one end of the chain and no hydroxyl groups at an opposed end of the chain

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

The polyurethane can be dispersed in the water

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS11319454B2Polyurethane-based binder dispersion
Publication Date: 2022.05.03 HEWLETT PACKARD DEVELOPMENT COMPANY LP
  • US11319454B2 patent drawing
  • US11319454B2 patent drawing
  • US11319454B2 patent drawing

AI summary

A polyurethane-based binder dispersion is described. The polyurethane based binder dispersion comprises: a polyurethane, which comprises: (A) a polyisocyanate; (B) a first polyol having a chain with two hydroxyl functional groups at one end of the chain and no hydroxyl groups at an opposed end of the chain; (C) a second polyol having a chain with two hydroxyl functional groups at both ends of the chain; (D) a carboxylic acid functional group with two hydroxyl functional groups; and (E) a compound shown in formula (1): m(M+) n(X)—R—Y— (1), wherein m is 0 or 1, M is a metal, n is 2 to 10, X is an amino group, R is a C1 to C18 alkyl group, a C6 to C30 aromatic compound or a C4 to C20 aliphatic cyclic compound, and Y is SO3- or SO3H, with the proviso that when m is 0, Y is SO3H and when m is 1, Y is SO3-.