Rigid Polyurethane Foam Composite Profiles Deformation

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Solution Overview

Problem

Existing methods for producing composite profiles with metal shells and rigid polyurethane foam for window and door frames face issues such as deformation during high-temperature painting, poor mechanical properties at low temperatures, and dust generation during cutting, often requiring inorganic fillers that can be detrimental.

Innovation Solution

A method involving the use of polyisocyanate, polyfunctional isocyanate-reactive compounds, blowing agents like formic acid, flame retardants, and catalysts to form rigid polyurethane foam without inorganic fillers, ensuring complete filling and maintaining mechanical integrity and preventing deformation during painting.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If inorganic fillers are added to rigid polyurethane foam to prevent deformation during high-temperature painting, then deformation is reduced, but dust generation during cutting increases and mechanical flexibility deteriorates

Engineering Contradiction:
Improvedimensional stability during paintingVSAvoiddust generation during cutting
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and removes inorganic fillers from the rigid polyurethane foam composition while maintaining dimensional stability during painting through optimized foam formulation and controlled foaming process, thereby eliminating dust generation during cutting operations

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition parameters of the rigid polyurethane foam by using specific polyol and isocyanate ratios, along with controlled blowing agents, to achieve dimensional stability without requiring inorganic fillers, thus preventing dust generation

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If inorganic fillers are added to rigid polyurethane foam to prevent deformation during high-temperature painting, then deformation is reduced, but mechanical flexibility and cold-temperature properties deteriorate

Engineering Contradiction:
Improvedimensional stability during paintingVSAvoidmechanical flexibility at low temperatures
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The invention removes inorganic fillers from the foam composition and replaces them with optimized polymeric components that maintain both dimensional stability during painting and mechanical flexibility at low temperatures

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention uses a composite formulation of organic polymers, polyols, and isocyanates to create a homogeneous rigid polyurethane foam that provides both dimensional stability during high-temperature painting and maintains mechanical flexibility at low temperatures without inorganic fillers

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If the cavity is only partially filled with polyurethane foam to avoid deformation, then some deformation is prevented, but thermal insulation properties deteriorate

Engineering Contradiction:
Improvedimensional stabilityVSAvoidthermal insulation performance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention changes the foaming parameters and chemical composition to enable complete cavity filling while maintaining dimensional stability, achieving both full thermal insulation coverage and resistance to deformation during painting

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses controlled excess foaming with optimized chemistry to ensure complete filling of the cavity between metal shells and polyamide webs, achieving full thermal insulation while the foam's chemical composition prevents deformation

Inventive Principle:
Principle #16Partial or excessive action

4Manufacturing precision

If conventional foam formulations with inorganic fillers are used, then dimensional stability during painting is improved, but brittleness increases and cold flexibility is lost

Engineering Contradiction:
Improvedimensional stability during paintingVSAvoidcold flexibility and processability
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The invention changes the chemical parameters by using specific polyol types, isocyanate indices, and blowing agent combinations to create a foam that remains flexible at low temperatures while maintaining dimensional stability during painting, eliminating the need for inorganic fillers

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a homogeneous composite polymeric material with optimized molecular structure that provides both dimensional stability during high-temperature painting and maintains flexibility at low temperatures, replacing inorganic filler-based formulations

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution prevents deformation during high-temperature painting, maintains mechanical properties at low temperatures, and reduces dust generation during processing, while avoiding the drawbacks of inorganic fillers.

Implementation Method 1

deformation of the composite elements due to the gas expansion in the rigid polyurethane foam

Methodology Applied
Scientific EffectGas expansion:

Implementation Method 2

the different thermal expansion of aluminum and rigid polyurethane foam

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 3

one or more blowing agents at least comprising formic acid

Methodology Applied
Scientific EffectDecomposition reaction: Decomposition (biological)

Data Source

PatentEP2900445B1Method for manufacturing composite profiles
Publication Date: 2017.03.01 BASF SE
  • EP2900445B1 patent drawing
  • EP2900445B1 patent drawing
  • EP2900445B1 patent drawing

AI summary

The invention relates to a method for producing composite profiled elements comprising at least two metal shells which are connected by connecting pieces made of a thermoplastic material and comprising a core made of rigid polyurethane foam. The method has the steps of introducing the starting components of the rigid polyurethane foam into a cavity formed by the metal shells, wherein the rigid polyurethane foam is formed, and subsequently coating the outer surface of the composite profile using a powder coating or a baking enamel, said rigid polyurethane foam being obtained by reacting the following components: A) at least one polyisocyanate, B) at least one multifunctional compound which is reactive towards isocyanates, C) one or more propellants at least comprising formic acid, D) optionally one or more flame retardants, E) optionally one or more catalysts, and F) optionally other auxiliary agents or additives. The starting components of the rigid polyurethane foam do not contain inorganic fillers.