Polyurethane Heat Storage Material With Solid-Solid Phase Transition
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Solution Overview
Problem
Conventional polyurethanes for heat storage materials suffer from inadequate heat storage performance, shape change due to heating and cooling, and poor heat resistance, with additives often separating and causing poor appearance, and existing heat storage systems have limitations on shape and potential leakage.
Innovation Solution
A polyurethane composition containing a structural unit derived from an isocyanate with an average number of functional groups of 2.1 or more and a structural unit derived from a polyalkylene ether glycol, with specific ratios and catalysts, achieving a solid-solid phase transition and improved heat storage properties.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Shape
If conventional polyurethane is used for heat storage material, then it can be processed into various shapes with good elasticity and mechanical strength, but it changes shape due to heating and cooling and has insufficient heat storage performance
Solution Approach 1:
The patent utilizes solid-solid phase transition of the polyurethane itself as the heat storage mechanism. The polyurethane undergoes a reversible phase transition between different solid states, absorbing and releasing heat while maintaining its shape. This eliminates the need for encapsulated phase change materials that cause shape changes, as the polyurethane matrix itself performs both structural support and heat storage functions.
Solution Approach 2:
The patent creates a composite polyurethane system by incorporating specific additives (such as metal salts, oxides, or other compounds) into the polyurethane matrix. These additives modify the polyurethane's thermal properties to enhance heat storage capacity and heat resistance while maintaining shape stability. The composite structure allows the material to retain its elastic and mechanical properties while achieving superior heat storage performance.
2Reliability
If additives having heat storage function are added to polyurethane, then heat storage performance is improved, but additives are extracted and separated causing poor appearance and poor heat resistance
Solution Approach 1:
The patent extracts the heat storage function from separate encapsulated materials and integrates it directly into the polyurethane molecular structure through chemical modification. By incorporating phase transition-capable groups into the polyurethane chains themselves, the heat storage functionality becomes an intrinsic property of the polymer matrix, eliminating the need for separate additive materials that could be extracted or separated.
Solution Approach 2:
The patent merges the heat storage function with the polyurethane matrix by chemically bonding heat storage-capable groups to the polymer chains. This integration ensures that the heat storage components cannot be extracted or separated, as they are chemically part of the polyurethane structure. The unified structure maintains both heat storage performance and compositional stability simultaneously.
3Adaptability or versatility
If heat storage material is filled in sealed container, then shape limitation is avoided, but the enclosed material may leak out and application versatility is limited
Solution Approach 1:
The polyurethane material serves dual functions: it provides both the structural matrix and the heat storage functionality through its inherent phase transition properties. This self-sufficient design eliminates the need for separate containers or encapsulated materials, as the polyurethane itself performs both structural support and heat storage without requiring external containment.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The polyurethane exhibits excellent heat storage properties, heat resistance, and shape retainability without additives, with a solid-solid phase transition and stable performance under heating and cooling.
Implementation Method 1
achieve a solid-solid phase transition and improved heat storage properties
Implementation Method 2
exhibits excellent heat storage properties
Data Source
AI summary
Disclosed is a polyurethane containing a structural unit (A) derived from an aromatic compound having an isocyanate group with an average number of functional groups of 2.1 or more and a structural unit (B) derived from a polyalkylene ether glycol. It is possible to provide a polyurethane for a heat storage material having good heat storage properties and heat resistance, excellent moldability, and good shape retainability against heating and cooling, a heat storage material containing the polyurethane, and a heat storage molded body.


