Polyurethane Heat Storage Material With Solid-Solid Phase Transition

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Solution Overview

Problem

Conventional polyurethanes for heat storage materials suffer from inadequate heat storage performance, shape change due to heating and cooling, and poor heat resistance, with additives often separating and causing poor appearance, and existing heat storage systems have limitations on shape and potential leakage.

Innovation Solution

A polyurethane composition containing a structural unit derived from an isocyanate with an average number of functional groups of 2.1 or more and a structural unit derived from a polyalkylene ether glycol, with specific ratios and catalysts, achieving a solid-solid phase transition and improved heat storage properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If conventional polyurethane is used for heat storage material, then it can be processed into various shapes with good elasticity and mechanical strength, but it changes shape due to heating and cooling and has insufficient heat storage performance

Engineering Contradiction:
Improveshape retainabilityVSAvoidheat storage performance
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent utilizes solid-solid phase transition of the polyurethane itself as the heat storage mechanism. The polyurethane undergoes a reversible phase transition between different solid states, absorbing and releasing heat while maintaining its shape. This eliminates the need for encapsulated phase change materials that cause shape changes, as the polyurethane matrix itself performs both structural support and heat storage functions.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent creates a composite polyurethane system by incorporating specific additives (such as metal salts, oxides, or other compounds) into the polyurethane matrix. These additives modify the polyurethane's thermal properties to enhance heat storage capacity and heat resistance while maintaining shape stability. The composite structure allows the material to retain its elastic and mechanical properties while achieving superior heat storage performance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If additives having heat storage function are added to polyurethane, then heat storage performance is improved, but additives are extracted and separated causing poor appearance and poor heat resistance

Engineering Contradiction:
Improveheat storage performanceVSAvoidadditive stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent extracts the heat storage function from separate encapsulated materials and integrates it directly into the polyurethane molecular structure through chemical modification. By incorporating phase transition-capable groups into the polyurethane chains themselves, the heat storage functionality becomes an intrinsic property of the polymer matrix, eliminating the need for separate additive materials that could be extracted or separated.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent merges the heat storage function with the polyurethane matrix by chemically bonding heat storage-capable groups to the polymer chains. This integration ensures that the heat storage components cannot be extracted or separated, as they are chemically part of the polyurethane structure. The unified structure maintains both heat storage performance and compositional stability simultaneously.

Inventive Principle:
Principle #5Merging (Combining)

3Adaptability or versatility

If heat storage material is filled in sealed container, then shape limitation is avoided, but the enclosed material may leak out and application versatility is limited

Engineering Contradiction:
Improveapplication versatilityVSAvoidleakage prevention
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The polyurethane material serves dual functions: it provides both the structural matrix and the heat storage functionality through its inherent phase transition properties. This self-sufficient design eliminates the need for separate containers or encapsulated materials, as the polyurethane itself performs both structural support and heat storage without requiring external containment.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyurethane exhibits excellent heat storage properties, heat resistance, and shape retainability without additives, with a solid-solid phase transition and stable performance under heating and cooling.

Implementation Method 1

achieve a solid-solid phase transition and improved heat storage properties

Methodology Applied
Scientific EffectSolid-solid phase transition: Phase Change

Implementation Method 2

exhibits excellent heat storage properties

Methodology Applied
Scientific EffectHeat storage: Thermal Energy Storage

Data Source

PatentUS20250349943A1Polyurethane, method for producing polyurethane, heat storage material, assembled battery, and construction material
Publication Date: 2025.11.13 MITSUBISHI CHEM CORP
  • US20250349943A1 patent drawing
  • US20250349943A1 patent drawing
  • US20250349943A1 patent drawing

AI summary

Disclosed is a polyurethane containing a structural unit (A) derived from an aromatic compound having an isocyanate group with an average number of functional groups of 2.1 or more and a structural unit (B) derived from a polyalkylene ether glycol. It is possible to provide a polyurethane for a heat storage material having good heat storage properties and heat resistance, excellent moldability, and good shape retainability against heating and cooling, a heat storage material containing the polyurethane, and a heat storage molded body.