Polyurethane Micro-capsules for Self-repairing Concrete

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Solution Overview

Problem

Conventional concrete technologies fail to effectively self-diagnose and self-repair micro-cracks, as hollow fiber capsule methods are limited by uneven distribution, brittle material characteristics, and reduced concrete strength, making it difficult to address micro-crack repair efficiently and reliably.

Innovation Solution

The use of polyurethane polymer micro-capsules dispersed within the concrete, which are fabricated by mixing polyurethane micro-capsules with concrete and water in specific ratios, stirring, and allowing for curing to create a self-repairing concrete that can autonomously repair micro-cracks through capillary siphon effects and polymerization reactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hollow fiber capsules are used for self-repairing concrete, then self-repairing function is achieved, but uniform distribution in concrete is difficult and concrete strength is reduced

Engineering Contradiction:
Improveself-repairing functionVSAvoidconcrete strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the material parameters by replacing hollow fiber capsules with polyurethane polymer micro-capsules of smaller size (10-100 μm diameter). This parameter change enables uniform distribution throughout the concrete matrix while the smaller size prevents significant strength reduction. The micro-capsules maintain self-repairing functionality through controlled rupture at micro-crack sites.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs disposable micro-capsules that are designed to rupture when needed. These polyurethane micro-capsules contain repair agents that are released upon capsule rupture at crack sites, performing their self-repairing function once and then being consumed. This disposable nature allows widespread distribution without long-term structural concerns.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If hollow fiber capsules are used for self-repairing, then repair capability is provided, but premature rupture occurs during construction due to vibration

Engineering Contradiction:
Improveself-repairing capabilityVSAvoidpremature loss of restorative
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent modifies the mechanical parameters by using polyurethane polymer material with appropriate elasticity and strength for micro-capsule walls. The smaller size (10-100 μm) and optimized wall thickness provide sufficient resistance to construction vibrations while maintaining sensitivity to micro-crack stresses. This parameter optimization prevents premature rupture during handling and construction.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If hollow fiber capsules are used, then self-repairing is achieved, but micro-crack repair is limited due to capsule size and strength

Engineering Contradiction:
Improveself-repairing functionVSAvoidmicro-crack repair effectiveness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies segmentation by dividing the repair system into numerous tiny micro-capsules (10-100 μm) distributed throughout the concrete. This segmentation allows the capsules to target and respond to individual micro-cracks independently. The fine segmentation enables penetration into and repair of micro-crack networks that would be inaccessible to larger hollow fiber capsules.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the size parameter from millimeter-scale hollow fibers to micrometer-scale polyurethane micro-capsules. This 100-fold size reduction enables the capsules to effectively address micro-cracks while maintaining sufficient wall strength through optimized polyurethane formulation and wall thickness control.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If hollow fiber capsules are used, then repair agents are introduced, but concrete strength is reduced due to introduced defects

Engineering Contradiction:
Improveself-repairing capabilityVSAvoidconcrete strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses inexpensive polyurethane micro-capsules as temporary, disposable elements embedded in the concrete. These micro-capsules serve their purpose by rupturing at micro-cracks to release repair agents, then being consumed in the process. Their temporary presence and small size minimize negative impact on concrete strength compared to permanent inclusions.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyurethane polymer micro-capsule concrete achieves improved mechanical performance and effective self-repair of micro-cracks, enhancing the durability and service life of concrete structures by ensuring uniform distribution and repeated repair capabilities without compromising the concrete's strength.

Implementation Method 1

self-repairing concrete that can autonomously repair micro-cracks through capillary siphon effects and polymerization reactions

Methodology Applied
Scientific EffectCapillary siphon effect: Capillary Action

Implementation Method 2

self-repairing concrete that can autonomously repair micro-cracks through capillary siphon effects and polymerization reactions

Methodology Applied
Scientific EffectPolymerization reaction: Photopolymerisation

Data Source

PatentUS8222323B2Self-repairing concrete having polyurethane polymer micro-capsules and method for fabricating the same
Publication Date: 2012.07.17 SHENZHEN HUABAO NICE FRIENDS TECHNOLOGY CO LTD

AI summary

A self-repairing concrete includes polyurethane polymer micro-capsules, in which the polyurethane polymer micro-capsules are mixed for a fixed function of micro-cracks. The quality mixture ratio is: concrete/micro capsules/water=100:1-15:15-50. The manufacturing method is weighing a full amount of water in a container, adding polyurethane polymer micro-capsules, stirring, until fully dispersed microcapsules; pouring the water into the mixing container, adding the corresponding quality of cement; stirring; adding sand and gravel filling materials, conducting worksite watering, ⅓ volume for each time, vibrating, and air exhausting; until the slurry filling mold.