Polyurethane Mounting Pad Uniform Pore Formation

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Solution Overview

Problem

Existing mounting pads for semiconductor and display device polishing have irregularly distributed internal pores, leading to poor cushion properties, non-uniform contact, and inadequate compressibility and compression recovery, which hinder precise polishing.

Innovation Solution

A polyurethane resin composition incorporating C9-15 alkyl benzene sulfonic acid or its salt and DMF solvent is used to form mounting pads with uniformly sized and distributed long and large pores, enhancing compressibility and compression recovery while maintaining low density.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional mounting pads are used with irregularly distributed pores, then manufacturing is simpler, but compressibility and compression recovery rate are poor

Engineering Contradiction:
Improvecompressibility and compression recovery rateVSAvoiduniformity of pore distribution
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent changes the chemical parameters of the polyurethane resin composition by incorporating specific ratios of polyether polyol and polyester polyol (1:4 to 4:1 weight ratio), along with specific catalysts and surfactants, to control the pore formation process and achieve uniform long and large pores with controlled cell structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite polyurethane resin system combining polyether polyol and polyester polyol in specific ratios, along with multiple additives including catalysts, surfactants, and blowing agents, to create a mounting pad with optimized pore structure that achieves both high compressibility and uniform pore distribution

Inventive Principle:
Principle #40Composite materials

2Reliability

If mounting pads have non-uniform pore size and distribution, then manufacturing is easier, but cushion property and adsorption to subject are insufficient

Engineering Contradiction:
Improvecushion property and adsorptionVSAvoiduniformity of pore distribution
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent optimizes chemical composition parameters including the ratio of polyether to polyester polyol (1:4 to 4:1), catalyst types and concentrations, and surfactant formulations to control phase separation and foam cell formation, resulting in uniform long and large pores that provide consistent cushioning and adsorption properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent deliberately creates a controlled porous structure with uniform long and large pores through chemical composition control and foaming process optimization, where the pore structure is designed to provide both cushioning effect and adsorption capability for the subject to be polished

Inventive Principle:
Principle #31Porous materials

3Reliability

If mounting pads have irregular pore distribution, then manufacturing is simpler, but water repellency and uniform contact are insufficient

Engineering Contradiction:
Improvewater repellency and uniform contactVSAvoiduniformity of pore distribution
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent modifies chemical composition parameters including adding specific surfactants and controlling the ratio of polyether and polyester polyols to achieve uniform pore distribution and controlled hydrophobicity, ensuring water repellency and uniform contact during polishing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates uniform local properties throughout the mounting pad by controlling pore size and distribution uniformly, ensuring that every region of the pad provides consistent water repellency and contact quality with the subject being polished

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting mounting pads exhibit improved compressibility and compression recovery rates, ensuring uniform contact and minimizing polishing faults by uniformly dispersing air across the polishing area, thus enhancing polishing precision.

Implementation Method 1

phase separation of the ingredients of the resin composition, for example phase separation of the polyurethane resin, water, and the organic solvent occurs, whereby a polyurethane resin including a plurality of pores formed therein may be obtained

Methodology Applied
Scientific EffectPhase separation:

Implementation Method 2

high compressibility and compression recovery rate

Methodology Applied
Scientific EffectElastic recovery: Elastic Recovery

Data Source

PatentUS8481149B2Polyurethane resin composition for mounting pad and polyurethane mounting pad using the same
Publication Date: 2013.07.09 LG CHEM LTD
  • US8481149B2 patent drawing
  • US8481149B2 patent drawing
  • US8481149B2 patent drawing

AI summary

This disclosure relates to a polyurethane resin composition for a mounting pad, including a polyurethane resin, C9-15 alkyl benzene sulfonic acid or a salt thereof, and a DMF solvent, and a polyurethane mounting pad using the same, whereby long and large pores may be uniformly formed thereinside to provide a mounting pad having low hardness, excellent compressibility, and a high compression modulus.