Polyurethane Adduct Composition for Residue-Free Stain Removal

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Solution Overview

Problem

Existing compositions for cleaning textiles, such as carpets and clothing, often result in inconsistent stain removal and leave residues due to the use of certain agents.

Innovation Solution

A composition comprising hydrogen peroxide and a polyurethane adduct of an ethylene oxide/propylene oxide copolymer reacted with hexamethylene diisocyanate, used as a pre-treatment in laundry or fabric washing, which acts as a softening agent and enhances stain removal without leaving residues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If standard cleaning agents are used for stain removal, then cleaning effectiveness is improved, but residues are left on the fabric

Engineering Contradiction:
Improvestain removal effectivenessVSAvoidresidue on fabric
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the cleaning composition by using hydrogen peroxide as the active cleaning agent and incorporating a specific polyurethane softening agent (sodium hydrogen sulphite adduct of ethylene oxide/propylene oxide copolymer reacted with hexamethylene diisocyanate) at 0.1-0.8 wt%. This parameter change allows effective stain removal through oxidation while the polyurethane ensures complete rinsability without residue formation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite cleaning system combining hydrogen peroxide (oxidizing agent) with a specific polyurethane softening agent. This composite formulation achieves synergistic effects where the hydrogen peroxide provides stain removal power and the polyurethane component ensures residue-free cleaning, resolving the contradiction between effectiveness and residue prevention.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If simple spray and rub method is used, then ease of operation is improved, but cleaning consistency deteriorates

Engineering Contradiction:
Improveapplication simplicityVSAvoidcleaning consistency
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent optimizes the chemical composition parameters including hydrogen peroxide concentration (1-12 wt%), polyurethane content (0.1-0.8 wt%), and pH balance to create a formulation that works consistently across different application methods. The specific ratio of ethylene oxide to propylene oxide units in the polyurethane is controlled to ensure predictable performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composition is formulated to be self-activating upon contact with the fabric and stain, requiring minimal user intervention. The hydrogen peroxide naturally activates to produce oxygen for stain breakdown, and the polyurethane automatically provides softening and rinsability benefits without requiring precise application technique from the user.

Inventive Principle:
Principle #25Self-service

3Reliability

If polyurethane softening agent is added to enhance cleaning, then cleaning performance is improved, but formulation complexity increases

Engineering Contradiction:
Improvecleaning performanceVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The polyurethane softening agent serves multiple functions simultaneously: it acts as a fabric softener, enhances stain removal performance, provides rinse-release properties to prevent residue, and contributes to the overall stability of the hydrogen peroxide formulation. This multi-functionality reduces the need for additional separate ingredients.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent specifies precise parameter ranges for the polyurethane (0.1-0.8 wt%, specific molecular structure with ethylene oxide/propylene oxide copolymer and hexamethylene diisocyanate) to optimize performance while maintaining formulation simplicity. These controlled parameters ensure consistent results without requiring complex formulation adjustments.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves better stain removal performance compared to standard softening agents, delivering effective cleaning benefits without residue, as demonstrated in comparative testing against reference additives.

Implementation Method 1

hydrogen peroxide...acts as a softening agent and enhances stain removal

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

The source of oxygen is present in an amount of up to 13wt%...The source of oxygen is hydrogen peroxide

Methodology Applied
Scientific EffectDecomposition of hydrogen peroxide: Decomposition (biological)

Implementation Method 3

the polyurethane is a sodium hydrogen sulphite adduct of an ethylene oxide/propylene oxide copolymer reacted with hexamethylene diisocyanate...acts as a softening agent

Methodology Applied
Scientific EffectPolymer-fiber interaction:

Data Source

PatentEP3110936B1composition
Publication Date: 2019.05.15 RECKITT BENCKISER (BRANDS) LTD

AI summary

A composition comprises a source of oxygen and a polyurethane for use in a treatment operation in cleaning a fabric material.