Polyvinyl Ester Adhesive Shear Stability

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Solution Overview

Problem

Existing dispersion adhesives based on polyvinyl esters face challenges in machine application processes due to contamination and instability under high shear forces, leading to machine downtime and inefficiencies in industrial production.

Innovation Solution

The use of polyvinyl esters stabilized with a combination of high-viscosity and medium-viscosity polyvinyl alcohols, along with optional low-viscosity polyvinyl alcohols, to enhance stability and control adhesive application, preventing contamination and ensuring precise application in mechanical processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If dispersion adhesives are applied using mechanical application processes (nozzle or roller systems), then industrial production efficiency is improved, but contamination occurs due to imprecise or uncontrolled adhesive application

Engineering Contradiction:
Improveindustrial production efficiencyVSAvoidadhesive contamination
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the rheological parameters of the dispersion adhesive by adjusting its viscosity and shear-thinning characteristics. This enables the adhesive to be precisely controlled during mechanical application processes, preventing uncontrolled spraying and contamination while maintaining high production efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements a feedback mechanism where the adhesive formulation is designed to respond to applied shear stress. The adhesive's flow properties automatically adjust based on the mechanical stress applied during nozzle or roller application, enabling self-regulation that prevents contamination without requiring additional control systems

Inventive Principle:
Principle #23Feedback

2Manufacturing precision

If high cycle frequencies of nozzle valves (up to 1000/second) are used for precise adhesive application, then application precision is improved, but the adhesive becomes unstable under extreme shear forces

Engineering Contradiction:
Improveadhesive application precisionVSAvoidadhesive stability under shear
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent specifically engineers the adhesive's viscosity and shear-thinning parameters to remain stable under extreme shear conditions. The adhesive maintains its functional properties even when exposed to shear forces from valve cycling at frequencies up to 1000/second, enabling precise application without degradation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite polymer system combining polyvinyl esters with carefully selected polyvinyl alcohols. This composite formulation provides enhanced stability under high shear forces while maintaining the desired application properties, resolving the contradiction between precision and stability

Inventive Principle:
Principle #40Composite materials

3Speed

If conventional dispersion adhesives are used in nozzle application systems, then application speed is maintained, but cone-shaped deposits form at the nozzle exit point that deflect the adhesive jet

Engineering Contradiction:
Improveadhesive application speedVSAvoidadhesive jet control
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The patent modifies the adhesive's flow parameters, particularly its viscosity and shear-thinning behavior, to prevent deposit formation. The adjusted parameters ensure smooth adhesive flow through the nozzle without cone-shaped deposits, maintaining both application speed and jet precision

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP3083728B1Process for the application of adhesive dispersions
Publication Date: 2018.02.07 WACKER CHEMIE AG

AI summary

The invention relates to methods for applying adhesives in the form of aqueous dispersions (dispersion adhesives) containing one or more polyvinyl esters and, optionally, one or more additives using mechanical application processes, characterized in that the polyvinyl esters are stabilized by at least two polyvinyl alcohols, at least one of which has a viscosity of 36 to 60 mPas (high-viscosity polyvinyl alcohol) and at least one of which has a viscosity of 19 to 35 mPas (medium-viscosity polyvinyl alcohol).