Porous Binder Coating for Lithium Battery Adhesion

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Solution Overview

Problem

Lithium secondary batteries face issues with weak adhesion strength between the electrode and separator, affecting battery performance and safety, particularly due to challenges in forming a thin, porous binder layer.

Innovation Solution

An electrode with a porous binder coating layer formed using a screen printing method with a mesh, utilizing a polyvinylidene fluoride (PVdF)-based polymer binder, applied in a thickness of 0.5 to 5 μm, which enhances adhesion while minimizing output degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a binder layer is formed by inducing phase separation on the separator surface, then adhesion strength between electrode and separator is improved, but the binder layer becomes difficult to thin

Engineering Contradiction:
Improveadhesion strengthVSAvoidbinder layer thickness
Core Design Contradiction:
StrengthVSLength of moving object

Solution Approach 1:

The invention changes the formation method parameter from phase separation induction to screen printing application, enabling precise control of binder layer thickness while maintaining adhesion strength. The screen printing method allows the binder layer to be formed at a controlled thickness of 0.5 to 5 μm, resolving the contradiction between achieving strong adhesion and maintaining thin layer structure.

Inventive Principle:
Principle #35Parameter changes

2Power

If the binder layer is formed as a thin film for excellent battery output, then output performance is improved, but adhesion strength with separator deteriorates

Engineering Contradiction:
Improvebattery outputVSAvoidadhesion strength
Core Design Contradiction:
PowerVSStrength

Solution Approach 1:

The invention optimizes the binder layer thickness parameter to a specific range of 0.5 to 5 μm through screen printing, achieving a balance where the layer is thin enough to maintain excellent output performance while being thick enough to provide sufficient adhesion strength. This parameter optimization resolves the contradiction between output performance and adhesion strength.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The screen printing method uses a mesh structure that allows precise control of material deposition through controlled application and drying processes, enabling the formation of uniformly thin binder layers that maintain both electrical performance and mechanical adhesion.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Strength

If the binder layer thickness is increased to improve adhesion, then adhesion strength is improved, but output performance deteriorates

Engineering Contradiction:
Improveadhesion strengthVSAvoidoutput performance
Core Design Contradiction:
StrengthVSPower

Solution Approach 1:

The invention establishes an optimal thickness parameter range of 0.5 to 5 μm for the binder layer, which is thin enough to preserve output performance while sufficient for adhesion. This precise parameter control through screen printing resolves the contradiction by finding the optimal balance point between these two competing requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The porous binder coating layer improves adhesion strength between the electrode and separator, maintaining battery performance and safety while preventing output degradation.

Implementation Method 1

coating the binder emulsion acquired at step (S20) on a surface of the active material layer of the electrode in a screen printing method using a mesh to form a binder coating layer of a porous structure

Methodology Applied
Scientific EffectScreen printing:

Implementation Method 2

The coated mesh pattern may be dried during the rotation of the mesh roll and the winding of the electrode

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS10468663B2Electrode with porous binder coating layer, method for manufacturing the same, and lithium secondary battery comprising the same
Publication Date: 2019.11.05 LG ENERGY SOLUTION LTD
  • US10468663B2 patent drawing
  • US10468663B2 patent drawing

AI summary

An electrode with a porous binder coating layer may be manufactured in a method including (S10) a step of preparing the electrode including an active material layer formed on at least one surface of a current collector; (S20) a step of acquiring a binder emulsion by adding a binder to a dispersion medium; and (S30) a step of coating the binder emulsion acquired at the step (S20) on a surface of the active material layer of the electrode in a screen printing method using a mesh to form a binder coating layer of a porous structure.