Porous Carbon Material Phase Separation Pore Structure

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Solution Overview

Problem

Existing porous carbon materials struggle to create a structure with both continuous and non-continuous pores, which limits their application in composite materials and hinders the efficient filling and use of fluids due to unidirectional pore formation during activation processes.

Innovation Solution

A process involving a carbonizable resin and an eliminable resin, mixed in specific proportions, undergoes phase separation and fixation without chemical reactions, resulting in a porous carbon material with a continuous porous structure and a portion without continuous pores, enhancing electrical and thermal conductivity, and mechanical strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If activation process is used to form pores from surface toward inner part, then porous carbon material can be produced at low cost, but continuous communicating pores cannot be formed

Engineering Contradiction:
Improveproduction costVSAvoidpore structure continuity
Core Design Contradiction:
Ease of manufactureVSShape

Solution Approach 1:

The patent applies preliminary action by forming the continuous porous structure through phase separation of carbonizable resin and eliminable resin before carbonization. The eliminable resin creates a pre-formed continuous pore network that persists through carbonization, unlike conventional activation that forms pores unidirectionally from the surface. This preliminary pore formation enables communicating pores to exist before any activation treatment.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes phase transitions by employing phase separation between carbonizable resin and eliminable resin to create distinct continuous and discontinuous phases. The eliminable resin phase forms continuous pores after removal, while the carbonizable resin forms the solid matrix. This phase separation mechanism fundamentally differs from conventional activation and enables continuous pore connectivity.

Inventive Principle:
Principle #36Phase transitions

2Productivity

If continuous porous structure is formed throughout the material, then fluid filling efficiency is improved, but electrical conductivity and mechanical strength decrease

Engineering Contradiction:
Improvefluid filling efficiencyVSAvoidmechanical strength and electrical conductivity
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent applies local quality by creating spatially differentiated pore structures: continuous pores are localized in specific regions to enable fluid filling, while discontinuous pores are localized in other regions to maintain mechanical strength and electrical conductivity. The phase separation process naturally creates this non-uniform distribution, with the eliminable resin forming continuous phases in certain areas and discontinuous phases in others.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the pore structure into continuous and discontinuous portions through phase separation. The eliminable resin forms a segmented continuous phase that provides fluid pathways, while the carbonizable resin forms a segmented matrix that maintains structural integrity. This segmentation allows different regions to fulfill different functions simultaneously.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material allows for efficient fluid filling and passage through continuous pores, while the non-continuous structure enhances electrical and thermal conductivity, and mechanical strength, particularly in resisting compressive rupture and maintaining structural integrity.

Implementation Method 1

a process involving a carbonizable resin and an eliminable resin, mixed in specific proportions, undergoes phase separation and fixation without chemical reactions

Methodology Applied
Scientific EffectPhase separation:

Implementation Method 2

enhancing electrical and thermal conductivity

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 3

enhancing electrical and thermal conductivity

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentEP2977350B1Porous carbon material, precursor for porous carbon material, process for producing precursor for porous carbon material, and process for producing porous carbon material
Publication Date: 2019.12.11 TORAY INDUSTRIES INC
  • EP2977350B1 patent drawingFigure 1
  • EP2977350B1 patent drawingFigure 2
  • EP2977350B1 patent drawingFigure 3

AI summary

The present invention provides: a porous carbon material which includes a portion having a continuous porous structure and a portion having no continuous porous structure and has even pore size and matrix size in the material center part thereof, thereby being easy to composite with other materials and being able to be used in various applications; a porous-carbon-material precursor; a process for producing the porous-carbon-material precursor; and a process for producing the porous carbon material. A porous carbon material of the invention is a porous carbon material which includes a portion having a continuous porous structure and a portion having substantially no continuous porous structure, in which the portion having the continuous porous structure has a structural period of 0.002 to 1 µm.