High Porosity Metal Oxide Catalyst Coatings for Vehicle Radiators

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Solution Overview

Problem

Current methods for addressing ground-level ozone pollution, particularly in the context of vehicle emissions, face challenges in long-term effectiveness and efficient manufacturing, as they often rely on direct treatment processes that may not maintain catalytic activity over the lifespan of vehicle components like radiators.

Innovation Solution

A catalysis composition comprising a metal catalyst and a support material, with the metal catalyst impregnated in the support material at specific ratios, is applied to vehicle radiators to convert ozone and other pollutants into less harmful compounds, maintaining catalytic activity and reducing ozone concentrations by over 30%.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If direct treatment processes are used to convert ozone at ground level, then ozone conversion is achieved, but catalytic activity is not maintained over the lifespan of vehicle components

Engineering Contradiction:
Improvecatalytic activity maintenanceVSAvoidlifespan of vehicle components
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent employs porous ceramic washcoat materials with high surface area and controlled pore structures to support the catalyst. The porous structure provides extensive surface area for catalyst dispersion while allowing ozone diffusion, maintaining catalytic activity throughout the component lifespan. The pore size distribution is optimized to balance reactant access and catalyst stability over time.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention uses composite catalyst formulations combining multiple metal oxides (e.g., manganese oxide, cerium oxide, cobalt oxide) with support materials. These composite materials synergistically enhance both the initial catalytic activity and long-term stability, preventing deactivation mechanisms such as sintering and poisoning that would otherwise limit the duration of effective operation.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If catalyst coating is applied to radiator surfaces, then ozone treatment is achieved, but heat exchange functionality may be impacted

Engineering Contradiction:
Improveozone pollutionVSAvoidheat exchange efficiency
Core Design Contradiction:
Object-generated harmful factorsVSTemperature

Solution Approach 1:

The catalyst coating is applied with spatially varying properties: the washcoat thickness and catalyst loading are optimized for different regions of the radiator surface based on local flow conditions and temperature. This ensures effective ozone treatment in high-velocity regions while maintaining thermal performance in heat exchange critical areas.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent optimizes coating parameters including thickness (typically 1-10 micrometers), porosity (50-80%), and catalyst concentration to achieve a balance between ozone conversion efficiency and thermal conductivity. The coating parameters are adjusted based on the specific radiator application to minimize impact on heat exchange while maximizing pollutant treatment.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described composition effectively reduces ozone concentrations in the atmosphere by maintaining catalytic activity over the lifespan of vehicle components, ensuring long-term pollutant conversion efficiency without significantly impacting the radiator's heat exchange functionality.

Implementation Method 1

ozone in the air that passes over catalyst coated surfaces, such as radiators, convert ozone molecules into oxygen molecules

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

a support material impregnated with the metal catalyst

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11794171B2High porosity metal oxide catalyst coatings
Publication Date: 2023.10.24 BASF MOBILE EMISSIONS CATALYSTS LLC
  • US11794171B2 patent drawing
  • US11794171B2 patent drawing
  • US11794171B2 patent drawing

AI summary

Disclosed in certain implementations is a catalysis composition that includes a metal catalyst and a support material impregnated with the metal catalyst.