Porous Ceramic Casting Element via Stereolithography

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Solution Overview

Problem

Current methods for fabricating complex gas turbine components, such as turbine blades with intricate cooling circuits, require multi-step processes involving wax dies and external ceramic shell coating, which are time-consuming and inefficient.

Innovation Solution

A ceramic resin is used, comprising a crosslinkable precursor, photoinitiator, ceramic particles, and pore-forming particles, which is formed through additive manufacturing processes like stereolithography to create a single-piece sacrificial ceramic casting element with controlled porosity, reducing the need for multiple core components and simplifying the casting process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional investment casting process with wax injection and external ceramic shell coating is used, then complex turbine blade components can be formed, but the process cycle time is excessive and manufacturing efficiency is low

Engineering Contradiction:
Improvecomplex component geometryVSAvoidprocess cycle time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent combines the ceramic core and external ceramic shell into a single integrated ceramic casting element formed by stereolithography. This eliminates the separate steps of wax injection, external shell coating, and core assembly, reducing process cycle time while maintaining the ability to form complex turbine blade geometries with internal cooling passages.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent replaces the mechanical multi-step investment casting process (wax injection, shell coating, assembly) with an additive manufacturing process (stereolithography) that directly forms the complete ceramic casting element in a single operation, significantly reducing manufacturing time.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Strength

If dense ceramic parts are produced by current stereolithography materials, then structural integrity is achieved, but leaching time becomes excessive due to lack of porosity

Engineering Contradiction:
Improveceramic part densityVSAvoidleaching time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The patent incorporates pore-forming particles into the stereolithography resin formulation. When the resin is cured and subsequently fired, these particles burn out leaving controlled porosity within the ceramic structure. This porosity provides channels for rapid leaching of the ceramic core material while maintaining sufficient structural integrity for casting applications.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent modifies the physical and chemical parameters of the stereolithography resin by adding pore-forming agents and adjusting the ceramic particle composition. These parameter changes enable the resin to form a ceramic structure with optimized porosity that balances structural strength with rapid leaching capability.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If multiple core components are used in conventional casting, then complex internal cooling circuits can be formed, but device complexity and manufacturing steps increase

Engineering Contradiction:
Improveinternal cooling circuit geometryVSAvoidnumber of core components
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent merges multiple separate core components into a single integrated ceramic casting element formed by stereolithography. The additive manufacturing process can directly create complex internal geometries including cooling circuits, impingement channels, and support structures within one monolithic component, eliminating the need for assembling multiple pieces.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent utilizes the three-dimensional capabilities of stereolithography to create complex internal geometries that would be difficult or impossible to achieve with conventional multi-piece assembly. The layer-by-layer additive process allows intricate cooling circuits and internal passages to be formed directly within the ceramic structure.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the rapid production of high-complexity ceramic cores with controlled porosity, reducing the overall process cycle time and eliminating the need for wax injection and external ceramic shell coating, resulting in cost and time savings while maintaining high-quality castings.

Implementation Method 1

applying light onto the ceramic resin such that the photoinitiator initiates polymerization of the crosslinkable precursor to form a crosslinked polymeric matrix

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 2

heating the crosslinked polymeric matrix to a first temperature to burn out the pore forming particles

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Data Source

PatentUS12054437B2Resin for production of porous ceramic stereolithography and methods of its use
Publication Date: 2024.08.06 GENERAL ELECTRIC CO
  • US12054437B2 patent drawing
  • US12054437B2 patent drawing

AI summary

A ceramic resin is provided, along with its methods of formation and use. The ceramic resin may include a crosslinkable precursor, a photoinitiator, ceramic particles, and pore forming particles. The ceramic resin may be utilized to form a ceramic casting element, such as via a method that includes forming a layer of the ceramic resin; applying light onto the ceramic resin such that the photoinitiator initiates polymerization of the crosslinkable precursor to form a crosslinked polymeric matrix setting the ceramic particles and the pore forming particles; and thereafter, heating the crosslinked polymeric matrix to a first temperature to burn out the pore forming particles.