Porous Ceramic Implant Coating via Polymer-Ceramic Sintering

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Solution Overview

Problem

Existing methods for producing porous ceramic surface layers on implants are limited in their ability to achieve predefined porosity and roughness, which is crucial for creating a strong mechanical bond between the implant and bone tissue, and are mainly applicable to bioceramic materials.

Innovation Solution

A method involving a mixture of polymer and ceramic materials applied directly to a substrate, followed by a sintering process, to create a porous ceramic surface layer with controlled porosity and roughness, utilizing a dispersion that includes a solvent and inorganic binder for optimal adhesion and biocompatibility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If sandblasting and etching processes are used to create pores on the implant surface, then mechanical strength of the bone-implant connection is improved, but the process complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvemechanical strength of bone-implant connectionVSAvoidprocess complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The porous surface layer is created as a separate coating layer on top of the implant substrate, rather than modifying the substrate itself. This segmentation allows the porous structure to be formed independently through the application and sintering of a ceramic slurry containing pore-forming agents, simplifying the overall manufacturing process while achieving the desired mechanical interlocking with bone tissue.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the physical and chemical parameters of the surface layer by applying a ceramic slurry with specific composition (containing pore-forming agents like hollow spheres or foams) and then sintering it at controlled temperatures. This transforms the surface from a dense state to a porous state with controlled porosity (30-70%), achieving mechanical strength without complex mechanical processing.

Inventive Principle:
Principle #35Parameter changes

2Strength

If a porous surface layer is applied to enhance mechanical bond strength, then the connection between implant and bone tissue is improved, but the manufacturing precision requirements increase

Engineering Contradiction:
Improvemechanical bond strengthVSAvoidpredefined porosity control
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

Pore-forming agents act as intermediaries in the ceramic slurry that create the porous structure during sintering. These agents (hollow spheres, foams, or other pore-forming materials) are temporarily introduced to define the pore geometry and are then removed or transformed during sintering, leaving behind the desired porous structure with controlled porosity and surface roughness that enhances mechanical bond strength.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If ceramic material is applied directly to the substrate, then adhesion and biocompatibility are improved, but the application process complexity increases

Engineering Contradiction:
Improveadhesion and biocompatibilityVSAvoidapplication process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention uses a composite ceramic slurry containing ceramic particles, pore-forming agents, and binding materials that can be applied directly to the implant substrate. This composite formulation allows the porous surface layer to be formed in a single application and sintering step, improving adhesion through direct contact with the substrate while maintaining biocompatibility through the use of appropriate ceramic materials.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the formation of a biocompatible porous ceramic surface layer with predefined porosity and roughness, enhancing the mechanical strength of the bond between the implant and bone tissue, and can be applied to various implant materials, including ceramic and technical ceramics.

Implementation Method 1

A porous, ceramic surface layer is a layer that has a ceramic composition with a predefined porosity and roughness in order to enable 'interlocking' of regrowing tissue with an implant

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 2

The application can preferably be carried out directly. Direct application means that the mixture is applied directly to the substrate and to the substrate without intermediate layers

Methodology Applied
Scientific EffectDirect application: Deposition (physical)

Data Source

PatentEP2051659B1Method for the production of a porous, ceramic surface layer
Publication Date: 2018.04.11 METOXIT
  • EP2051659B1 patent drawingFigure 1~2

AI summary

The present invention provides a method for the production of a porous, ceramic surface layer (10) on a substrate (1), wherein the method comprises the step of applying a mixture to the substrate (1), wherein the mixture comprises a polymer, and at least one ceramic material.