Porous CO2 Supply Unit for Uniform Electrode Distribution

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Solution Overview

Problem

Conventional carbon dioxide reduction devices face inefficiencies due to non-uniform supply of carbon dioxide to the reduction electrode, requiring energy-intensive stirring to disperse CO2 bubbles, increasing costs and environmental impact.

Innovation Solution

A carbon dioxide reduction device with a gas supply unit featuring multiple pores at the bottom of the reduction chamber, supplying CO2 as bubbles to uniformly elevate its concentration in the aqueous solution, eliminating the need for stirring and enhancing reaction efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If carbon dioxide is supplied through a tube to the reduction electrode, then the device structure is simple, but the carbon dioxide distribution is non-uniform reducing reaction efficiency

Engineering Contradiction:
Improvecarbon dioxide reduction reaction efficiencyVSAvoidcarbon dioxide supply structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The carbon dioxide supply structure is segmented into multiple pores distributed across the bottom surface of the reduction chamber, rather than using a single tube. This segmentation allows carbon dioxide to be supplied at multiple locations simultaneously, creating uniform bubble distribution across the reduction electrode surface and improving reaction efficiency without requiring complex external stirring mechanisms.

Inventive Principle:
Principle #1Segmentation

2Productivity

If stirring is used to disperse carbon dioxide bubbles uniformly, then carbon dioxide distribution improves, but energy consumption increases

Engineering Contradiction:
Improvecarbon dioxide reduction reaction efficiencyVSAvoidenergy consumption for stirring
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The carbon dioxide supply system performs self-service by using the carbon dioxide gas itself to create uniform distribution through the porous structure. The bubbles rising through the pores naturally disperse throughout the solution without requiring external mechanical stirring or additional energy input, eliminating the need for separate stirring mechanisms while maintaining uniform carbon dioxide distribution.

Inventive Principle:
Principle #25Self-service

3Ease of operation

If a single carbon dioxide supply tube is used, then the device is simple to operate, but carbon dioxide cannot be uniformly supplied to the electrode surface

Engineering Contradiction:
Improveoperation simplicityVSAvoidcarbon dioxide reduction reaction efficiency
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

A porous plate or porous structure is introduced at the bottom of the reduction chamber to distribute carbon dioxide uniformly. The porous material allows gas to pass through numerous small pores, creating fine bubbles that rise uniformly throughout the solution and reach the electrode surface evenly. This maintains operational simplicity while dramatically improving carbon dioxide distribution and reaction efficiency.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device improves the efficiency of the carbon dioxide reduction reaction by ensuring uniform CO2 distribution, as demonstrated by increased Faraday efficiency in production of hydrogen and other substances, while reducing energy consumption and environmental impact.

Implementation Method 1

A proton produced by the oxidation reaction of water in the oxidation electrode is transported to the reduction chamber via the proton exchange membrane

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Implementation Method 2

In the reduction electrode, hydrogen is produced by the reduction reaction of the proton

Methodology Applied
Scientific EffectElectrochemical reduction: Electrolysis

Implementation Method 3

carbon monoxide, methane, ethylene, methanol, ethanol, and formic acid, etc. are produced by the reduction reaction of carbon dioxide

Methodology Applied
Scientific EffectElectrochemical reduction: Electrolysis

Implementation Method 4

A proton produced by the oxidation reaction of water in the oxidation electrode

Methodology Applied
Scientific EffectOxidation reaction: Oxidation

Data Source

PatentUS12036526B2Carbon dioxide reduction device
Publication Date: 2024.07.16 NIPPON TELEGRAPH & TELEPHONE CORP
  • US12036526B2 patent drawing
  • US12036526B2 patent drawing
  • US12036526B2 patent drawing

AI summary

Improvement in the efficiency of carbon dioxide reduction reaction is achieved. A gas supply unit having a plurality of pores is established in a lower portion of a reduction chamber, and carbon dioxide is supplied as bubbles into an aqueous solution. This can elevate a concentration of carbon dioxide dissolved in the aqueous solution without stirring the aqueous solution using a stirring bar, and render the concentration uniform in the aqueous solution. Therefore, the efficiency of reduction reaction of carbon dioxide in a reduction electrode can be improved.