Porous Electrochromic Layer for Fast Response Speed

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Solution Overview

Problem

Existing electrochromic devices lack flexibility and high response speed, and their manufacturing processes often require high temperatures and complex procedures.

Innovation Solution

A multi-pore structure electrochromic device is developed, featuring a porous electrochromic layer with nanoparticle clusters and electrolyte, where the porous layer includes nanoparticles and metal oxides, and a simplified manufacturing method is used, involving a conductive paste applied to an electrode, heat-treated at reduced temperatures, and immersed in an electrochromic material solution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If a conventional electrochromic layer is used, then the device structure is simple, but the response speed is slow

Engineering Contradiction:
Improveresponse speedVSAvoidlayer structure complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The electrochromic layer is designed with a porous structure containing nanoparticle clusters distributed throughout the matrix. This porous architecture provides multiple pathways for ion transport and increases the effective surface area for electrochromic reactions, thereby significantly improving the response speed of the device without requiring complex multi-layer structures

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The electrochromic layer combines multiple materials including conductive polymer matrix, nanoparticle clusters (such as metal oxides), and electrochromic compounds into a composite structure. This composite approach leverages the advantages of each material component to achieve fast response speed while maintaining structural simplicity and functional integration

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If high temperature manufacturing is used, then the electrochromic layer forms properly, but the manufacturing cost and energy consumption increase

Engineering Contradiction:
Improvemanufacturing temperatureVSAvoidenergy consumption
Core Design Contradiction:
Ease of manufactureVSUse of energy by stationary object

Solution Approach 1:

The manufacturing process utilizes parameter changes by controlling the deposition and formation conditions at lower temperatures. By adjusting parameters such as solvent composition, deposition rate, and mild heating temperatures (below conventional high-temperature processing), the electrochromic layer forms properly with reduced energy consumption and lower manufacturing costs

Inventive Principle:
Principle #35Parameter changes

3Speed

If the surface area for electrochromic material adsorption is increased, then the response speed improves, but the device complexity increases

Engineering Contradiction:
Improveresponse speedVSAvoidstructural complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The porous matrix structure inherently provides large surface area for electrochromic material adsorption without requiring additional complex structural elements. The interconnected pores and high surface-to-volume ratio of the porous architecture enable extensive material distribution and rapid ion access, improving response speed while maintaining relatively simple device structure

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The nanoparticle clusters are locally distributed within the porous matrix at specific regions where electrochromic activity is needed. This localized concentration of functional materials maximizes the effective surface area for reactions in critical zones without uniformly complicating the entire device structure, achieving high response speed with controlled structural complexity

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device exhibits improved response speed and color properties, with increased surface area for electrochromic material adsorption, and can be manufactured at lower temperatures, making it suitable for flexible displays like smart windows and electronic paper.

Implementation Method 1

The porous electrochromic layer includes nanoparticle clusters, and each nanoparticle cluster includes a plurality of nanoparticles and an electrochromic material

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

Electrochromism is a phenomenon in which a color, displayed on an electrochromic display device, reversibly changes based on a direction of an electric field from a voltage applied to the display device

Methodology Applied
Scientific EffectElectrochromism: Electrochromism

Implementation Method 3

An electrochromic material is a material having electrochromism, e.g., a material whose optical characteristics reversibly change due to an electrochemical reduction-oxidation ("redox") reaction

Methodology Applied
Scientific EffectRedox reactions: Redox Reactions

Data Source

PatentUS8441708B2Electrochromic device and method of manufacturing the same
Publication Date: 2013.05.14 SAMSUNG ELECTRONICS CO LTD
  • US8441708B2 patent drawing
  • US8441708B2 patent drawing
  • US8441708B2 patent drawing

AI summary

An electrochromic device includes a first electrode, a second electrode disposed opposite the first electrode, a porous electrochromic layer disposed on the first electrode or the second electrode, and an electrolyte disposed between the first electrode and the second electrode. The porous electrochromic layer includes different sized nanoparticle clusters, and each nanoparticle cluster includes a plurality of nanoparticles and an electrochromic material.