Porous Electrode with Proton Affinity Groups for Fuel Cell Catalyst Support

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Solution Overview

Problem

Conventional fuel cell electrodes face inefficiencies due to incomplete catalyst utilization and catalyst agglomeration, leading to higher costs and reduced reaction efficiency, as well as issues with proton conduction in the absence of a polymer electrolyte.

Innovation Solution

A porous electrode with a three-dimensional skeleton and proton affinity groups supports a catalyst, ensuring efficient proton and electron separation and transport, utilizing a catalyst primarily on the surface for enhanced reaction efficiency and reduced catalyst usage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a porous electrode with polymer electrolyte coating is used to enable proton conduction, then proton transport is improved, but catalyst utilization deteriorates due to aggregation and reduced accessibility

Engineering Contradiction:
Improveproton conductionVSAvoidcatalyst utilization
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The electrode is divided into multiple layers with distinct functions: a porous support layer for catalyst dispersion and a separate polymer electrolyte layer for proton conduction. This segmentation allows each layer to optimize its specific function without interfering with the other, solving the contradiction between proton conduction and catalyst utilization.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A porous porousous support material acts as an intermediary between the catalyst particles and the polymer electrolyte. This intermediary structure provides both mechanical support for catalyst dispersion and pathways for proton transport, enabling both catalyst utilization and proton conduction to function effectively.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If more catalyst is used to improve reaction efficiency, then reaction rate increases, but cost increases due to catalyst expense

Engineering Contradiction:
Improvereaction efficiencyVSAvoidcatalyst amount
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The electrode structure creates local regions of high catalyst concentration on the porous support surface where reaction efficiency is maximized, while the overall catalyst quantity in the entire electrode is reduced. The porous structure provides high surface area per unit volume, allowing efficient local catalysis with minimal total catalyst.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The use of porous support materials provides a high surface area framework that disperses catalyst particles efficiently. This porous structure allows fuel to access catalyst sites throughout the electrode volume, achieving high reaction efficiency with reduced catalyst loading compared to dense electrode structures.

Inventive Principle:
Principle #31Porous materials

3Ease of manufacture

If catalyst particles are aggregated to simplify manufacturing, then manufacturing complexity decreases, but reaction efficiency deteriorates due to reduced surface area

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidreaction efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The porous support material is prepared in advance with its porous structure established before catalyst application. This preliminary preparation creates a pre-formed framework that naturally disperses catalyst particles during the impregnation process, achieving both manufacturing simplicity and high catalyst surface area without requiring complex post-processing steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The porous support material provides a physical framework that prevents catalyst particle aggregation through its porous structure. The pores physically separate catalyst particles while maintaining their accessibility to fuel, thereby preserving high surface area and reaction efficiency while simplifying the manufacturing process.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The porous electrode design enhances reaction efficiency by ensuring catalysts are effectively utilized and proton transport is facilitated, leading to improved fuel cell performance with reduced catalyst amounts and costs.

Implementation Method 1

a porous material composed of a three-dimensional skeleton

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 2

a substance having one or more types of proton affinity group is present on all or part of the three-dimensional skeleton surface

Methodology Applied
Scientific EffectProton affinity: Adsorption

Implementation Method 3

a catalyst for separating hydrogen into protons and electrons is further included in the electrode, with the catalyst being supported on the substance

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS7662505B2Porous electrode, and electrochemical element made using the same
Publication Date: 2010.02.16 PANASONIC HOLDINGS CORP
  • US7662505B2 patent drawing
  • US7662505B2 patent drawing
  • US7662505B2 patent drawing

AI summary

The primary object of the present invention is to provide an electrode with which an efficient electrode reaction will occur. The present invention relates to a porous electrode which is an electrode composed of a porous material having electron conductivity, wherein (1) the porous material comprises a three-dimensional skeleton, (2) a substance having one or more proton affinity groups is present on all or part of the three-dimensional skeleton surface, and (3) a catalyst for separating hydrogen into protons and electrons is further included, with the catalyst being supported on the substance.