Density Separation of Porous Plastics via Liquid Infiltration

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Solution Overview

Problem

Existing methods for separating plastics with overlapping densities, such as acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS), and contaminants like wood and rubber, are inefficient due to similar densities, leading to degraded plastic properties and processability issues.

Innovation Solution

The process involves two stages: first, air is forced out of the pores of porous materials using methods like boiling in a liquid solution, and second, a liquid solution is introduced to increase the density of these materials, allowing them to sink while plastics float, using an aqueous solution with controlled specific gravity and surface tension.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If gravity separation is used to separate plastics with overlapping densities, then the separation process is simple and economical, but the separation purity is low and contaminants remain

Engineering Contradiction:
Improveseparation process simplicityVSAvoidseparation purity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent modifies physical parameters of the porous materials (density, porosity, surface properties) through treatments such as solvent extraction, swelling, or coating to create sufficient density differences between plastic types and contaminants, enabling effective gravity separation that achieves both simplicity and high purity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces intermediary substances (solvents, surfactants, or density modification agents) that selectively interact with either the plastics or contaminants to enhance density contrast, allowing the simple gravity separation method to achieve contaminant removal rates exceeding 95% while maintaining process economy

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If density separation is used to remove porous contaminants like wood and rubber, then the process is inexpensive, but the contaminants cannot be effectively separated due to overlapping densities

Engineering Contradiction:
Improveprocess costVSAvoidcontaminant removal efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes physical parameters of porous contaminants through controlled swelling, drying, or density modification treatments to create distinguishable density differences from plastics, enabling inexpensive separation methods to reliably remove wood and rubber contaminants with removal rates exceeding 95%

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies localized treatments to porous contaminants (such as selective swelling agents or surface modifications) that alter their density or buoyancy characteristics without affecting the bulk plastics, allowing inexpensive separation processes to achieve reliable contaminant removal through enhanced local property differentiation

Inventive Principle:
Principle #3Local quality

3Device complexity

If conventional separation methods are used, then the process is simple, but plastic properties and processability are degraded due to contaminant presence

Engineering Contradiction:
Improveseparation system complexityVSAvoidplastic property quality
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent modifies physical parameters of either the plastics or contaminants (density, porosity, surface tension) through controlled treatments to create sufficient differentiation, enabling simple separation systems to achieve high purity plastics with contaminant removal rates exceeding 95%, thereby preserving plastic properties and processability without increasing system complexity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively separates overlapping density porous materials from plastics, achieving high removal rates of contaminants like wood and rubber, with over 95% wood and 90% foam removal, while minimizing plastic loss, thus enhancing the purity and processability of recovered plastics.

Implementation Method 1

air is forced out of the pores of porous materials using methods like boiling in a liquid solution

Methodology Applied
Scientific EffectBoiling: Boiling

Implementation Method 2

a liquid solution is introduced to increase the density of these materials

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

a liquid solution is introduced to increase the density of these materials

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 4

allowing them to sink while plastics float, using an aqueous solution with controlled specific gravity

Methodology Applied
Scientific EffectGravity separation: Gravitation

Data Source

PatentUS8083067B2Method for the separation of overlapping density porous materials from less porous materials
Publication Date: 2011.12.27 UCHICAGO ARGONNE LLC
  • US8083067B2 patent drawing
  • US8083067B2 patent drawing
  • US8083067B2 patent drawing

AI summary

Enhanced methods for separating of overlapping density porous materials are provided. The methods of the invention exploit the differences in the porosity of porous feed materials compared to that of the solid plastics. In the first stage, air is forced out of the pores of a porous feed material. In the second stage, a solution, having the appropriate density, is forced into the pores. This increases the density of the porous material relative to the density of the solid plastics. As a result, the porous material can be made to sink, while the solid plastics continue to float.