Potassium Phosphate Acetic Acid Scale Removal Composition

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Solution Overview

Problem

Conventional methods for preventing and removing scale deposits in subsea environments are ineffective, particularly in areas with strict environmental regulations, as they often use non-environmentally friendly chemicals and struggle with barium and strontium sulfate scales, which are difficult to inhibit and dissolve.

Innovation Solution

An aqueous composition comprising alkali metal phosphate compounds, such as potassium phosphate, and acetic acid, which is environmentally friendly and capable of dissolving scale deposits without requiring a shroud, and can be used in seawater environments, maintaining contact for a suitable period to separate scale deposits from surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional chemical-based scale inhibition techniques are used, then scale formation may be inhibited to some extent, but barium and strontium sulfate scales remain difficult to prevent and dissolve

Engineering Contradiction:
Improvescale inhibition effectivenessVSAvoiddifficulty in removing sulfate scales
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the cleaning composition by using alkali metal phosphate compounds (changing the anionic component) combined with organic acids, which fundamentally alters the dissolution mechanism for barium and strontium sulfate scales compared to conventional acid-based cleaners. This parameter change enables effective removal of sulfate scales that were previously resistant to conventional treatments.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If strong acids are used to dissolve scale deposits, then scale removal effectiveness is improved, but environmental safety and material compatibility deteriorate

Engineering Contradiction:
Improvescale removal effectivenessVSAvoidenvironmental impact and corrosion
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the traditionally harmful strong acids into environmentally benign organic acids (acetic, propionic, butyric acid) that maintain scale-dissolving effectiveness while eliminating the harmful environmental and corrosive effects. The alkali metal phosphate compounds enhance this benign acid system to achieve performance previously only attainable with harsh chemicals.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent uses biodegradable organic acids with short environmental persistence instead of persistent strong acids. These organic acids break down naturally, providing effective scale removal during use while minimizing long-term environmental harm, aligning with the disposable/short-living concept where the cleaning agent degrades after use rather than persisting in the environment.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If conventional scale removal methods are used in subsea environments, then scale deposits can be removed, but strict environmental regulations are violated

Engineering Contradiction:
Improvescale deposit removalVSAvoidenvironmental compliance
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent transforms conventional harmful chemical cleaners into environmentally safe formulations using alkali metal phosphate compounds and biodegradable organic acids. This conversion maintains effective scale removal capability while ensuring compliance with subsea environmental regulations, turning a previously harmful practice into an environmentally beneficial one.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively removes scale deposits while being environmentally safe, as it only uses chemicals listed on the OSPAR Convention's PLONOR database, ensuring minimal environmental impact and maintaining equipment functionality without damaging subsea materials.

Implementation Method 1

An aqueous composition comprising alkali metal phosphate compounds, such as potassium phosphate, and acetic acid, which is environmentally friendly and capable of dissolving scale deposits

Methodology Applied
Scientific EffectChemical dissolution: Chemical Bonding

Data Source

PatentUS9145508B2Composition for removing scale deposits
Publication Date: 2015.09.29 MACDERMID CANNING LTD

AI summary

An aqueous composition for removing scale deposits, especially on subsea equipment and a method of using the same. The aqueous composition comprises (a) a potassium phosphate compound; and (b) acetic acid. The composition is capable of dissolving away into seawater and poses little or no risk to the environment.