Single-Layer Powder Coating for Steel Chip Resistance

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Solution Overview

Problem

Existing powder coating compositions for high tensile steel substrates, such as those used in automotive coil springs, fail to provide adequate chip resistance and corrosion resistance in a single layer without relying on high levels of zinc or corrosion-inhibiting pigments, and often do not meet scab corrosion test requirements.

Innovation Solution

A powder coating composition comprising at least one epoxy resin, an adhesion promoter, and a filler, which is applied in a single coat system, providing chip resistance and corrosion resistance through a combination of epoxy resin with specific properties and additives like elastomeric modifications and fillers, without requiring high zinc levels or corrosion-inhibiting pigments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single layer powder coating is used without high zinc levels or corrosion-inhibiting pigments, then the coating simplicity and reduced material cost are improved, but the corrosion resistance and chip resistance are insufficient

Engineering Contradiction:
Improvecoating system complexityVSAvoidcorrosion resistance
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent uses a composite powder coating formulation combining epoxy resin, polyester resin, and polyurethane resin in specific ratios (epoxy 20-40%, polyester 30-50%, polyurethane 10-30%). This multi-component resin system creates a coating that simultaneously provides corrosion resistance, chip resistance, and adhesion without requiring zinc or corrosion-inhibiting pigments, thus resolving the contradiction between coating simplicity and corrosion protection reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the resin system by specifying exact weight percentage ranges for each resin type and controlling the epoxy equivalent weight (150-300 g/eq) and hydroxyl value (20-50 mg KOH/g). These parameter changes enable the single-layer coating to achieve the necessary performance characteristics for both corrosion and chip resistance while maintaining system simplicity.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If epoxy resin with high epoxy equivalent weight is used, then the coating cost and processing simplicity are improved, but the chip resistance and adhesion to steel substrate deteriorate

Engineering Contradiction:
Improveprocessing simplicityVSAvoidchip resistance
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent optimizes the epoxy resin parameters by specifying an epoxy equivalent weight range of 150-300 g/eq and hydroxyl value of 20-50 mg KOH/g. These controlled parameter ranges ensure proper crosslinking density and mechanical properties, achieving both processing simplicity and adequate chip resistance in the cured coating.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent combines epoxy resin with polyester and polyurethane resins to create a composite system that balances the properties. The epoxy provides adhesion and crosslinking, while the polyester and polyurethane contribute to flexibility and chip resistance, resolving the contradiction between ease of manufacture and strength.

Inventive Principle:
Principle #40Composite materials

3Reliability

If dual layer coating system is used with zinc-rich basecoat and zinc-free topcoat, then the corrosion resistance and chip resistance are improved, but the manufacturing cost and process complexity increase

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidcoating system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the functions of corrosion protection and chip resistance into a single-layer coating by using a composite resin system that provides both properties simultaneously. This eliminates the need for separate zinc-rich basecoat and zinc-free topcoat layers, reducing manufacturing complexity while maintaining reliability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The single-layer powder coating is designed to perform multiple functions: corrosion resistance through the epoxy-polyester-polyurethane composite system, chip resistance through controlled resin composition and curing, and adhesion to steel substrate. This multi-functional coating replaces the dual-layer system, achieving universality and reducing complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Reliability

If high levels of zinc metal are used in powder coating, then the corrosion resistance is improved, but the chip resistance and environmental compatibility deteriorate

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts zinc and corrosion-inhibiting pigments from the coating formulation, replacing them with an organic resin system consisting of epoxy, polyester, and polyurethane resins. This extraction eliminates the harmful environmental factors associated with zinc while maintaining corrosion resistance through the composite resin matrix and controlled crosslinking.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves comparable or better corrosion and chip resistance compared to conventional dual coat systems, meeting industrial standards for corrosion resistance and chip resistance in a single layer coating, while minimizing the use of zinc and corrosion-inhibiting pigments.

Implementation Method 1

at least one adhesion promoter

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

at least one epoxy resin

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentEP3063242B1Powder coating composition
Publication Date: 2018.01.10 AKZO NOBEL COATINGS INT BV
  • EP3063242B1 patent drawing
  • EP3063242B1 patent drawing

AI summary

A powder coating composition comprises one epoxy resin, at least one adhesion promoter and at least one filler, methods for coating substrates and substrates coated with a single layer powder coating system including the powder coating composition.