Power generation process utilizing fuel, liquid air and/or oxygen with zero co2 emissions

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Solution Overview

Problem

The electrical power network faces instability due to misalignment between energy supply and demand, exacerbated by the rigidity and discontinuity of traditional energy sources, and the environmental impact of high-emission power plants, while existing storage and sequestration technologies like LAES and oxy-combustion suffer from inefficiencies and high energy expenditure.

Innovation Solution

Integration of oxy-combustion technologies with liquid air energy storage (LAES) using a process that involves high-pressure gas turbines, direct or indirect heat exchange, and recycling of CO2 and water vapor to achieve efficient power production and liquefaction, thereby stabilizing the network and promoting renewable energy use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If oxy-combustion technologies are used for power production, then CO2 emissions are concentrated and can be sequestered, but the process requires energy-intensive separation of oxygen from nitrogen and liquefaction of CO2

Engineering Contradiction:
ImproveCO2 emissionsVSAvoidenergy expenditure for oxygen separation and CO2 liquefaction
Core Design Contradiction:
Object-generated harmful factorsVSUse of energy by moving object

Solution Approach 1:

The patent combines oxy-combustion power production with liquid air energy storage (LAES) in a single integrated system. The air separation unit produces both oxygen for combustion and liquid air for energy storage simultaneously, eliminating the need for separate oxygen production and CO2 liquefaction processes. This merging of functions reduces overall energy consumption while capturing CO2 emissions.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The liquid air produced in the LAES system serves multiple purposes: it acts as an energy storage medium for grid stabilization, provides a cold source for CO2 liquefaction, and can be used as an oxygen source for the combustor when evaporated. This multi-functionality reduces the need for separate systems and minimizes energy expenditure.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Quantity of substance

If liquid air energy storage (LAES) is used to stabilize the electrical power network, then energy storage capacity is increased, but the process requires high energy expenditure for air liquefaction

Engineering Contradiction:
Improveenergy storage capacityVSAvoidenergy expenditure for air liquefaction
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The patent integrates LAES with oxy-combustion power production, where the air separation unit simultaneously produces liquid air for storage and oxygen for combustion. This combined approach allows the system to store large quantities of energy while the combustion process provides heat that can be utilized in the air separation and CO2 liquefaction processes, reducing the net energy expenditure.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The system uses its own internal resources to reduce energy consumption: the heat from combustion is used in the air separation process, and the cold from liquid air evaporation is used for CO2 liquefaction. This self-service approach minimizes external energy input while maintaining high storage capacity.

Inventive Principle:
Principle #25Self-service

3Reliability

If hydroelectric and turbogas power plants are used to cover demand peaks, then network stability is improved, but hydroelectric space is limited and turbogas emits large amounts of greenhouse gases

Engineering Contradiction:
Improvenetwork stabilityVSAvoidgreenhouse gas emissions from turbogas
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent merges oxy-combustion power production with LAES to create a system that can rapidly respond to demand peaks. The stored liquid air can be quickly evaporated and used to drive the turbine, providing flexible power generation without greenhouse gas emissions, replacing the need for turbogas plants while maintaining network stability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The system changes the physical state of air from liquid (storage) to gas (power generation) on demand, enabling rapid response to load variations. This phase change allows the system to provide flexible power generation similar to hydroelectric and turbogas plants but without the associated limitations and emissions.

Inventive Principle:
Principle #35Parameter changes

4Object-generated harmful factors

If renewable energy sources like solar and wind are used to replace combustion power plants, then environmental impact is reduced, but the discontinuity of these sources aggravates network instability

Engineering Contradiction:
Improveenvironmental impactVSAvoidnetwork stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The system performs preliminary action by storing energy in liquid air form during periods of excess renewable energy generation. This stored energy can then be rapidly deployed when renewable sources are unavailable, ensuring continuous power supply and maintaining network stability while keeping environmental impact low.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system recovers and stores excess energy from renewable sources by converting it to liquid air through the air separation unit. This recovered energy is then available for later use, transforming the discontinuous nature of renewable sources into a reliable, on-demand power supply without compromising environmental benefits.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This integration enhances network stability, increases energy efficiency, and reduces environmental impact by achieving a high efficiency of about 80% in fuel use, while extending the life of non-renewable resources and promoting the use of renewable energy sources.

Implementation Method 1

producing, in a combustor, an exhaust gas mainly composed of carbon dioxide and water vapor

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 2

expanding said exhaust gas in a first expander with power production

Methodology Applied
Scientific EffectExpansion:

Implementation Method 3

cooling the expanded exhaust gas in a heat recovery unit, thus obtaining a cooled expanded exhaust gas and a first heated working fluid

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 4

separating a first portion of condensed water vapor in a first separator

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 5

pumping a portion of the condensed water vapor and recycling it to the combustor

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 6

cooling said partially dehydrated exhaust gas in a first heat exchanger, thus obtaining a further cooled exhaust gas and a second heated working fluid

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 7

separating a second portion of condensed water vapor in a second separator

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 8

subjecting said further dehydrated exhaust gas to a yet further dehydration in a dehydration unit

Methodology Applied
Scientific EffectDehydration:

Implementation Method 9

liquefying the CO2 in said exhaust gas mainly composed of CO2 in a liquefaction unit

Methodology Applied
Scientific EffectLiquefaction: Phase Change

Data Source

PatentUS20230408192A1Power generation process utilizing fuel, liquid air and/or oxygen with zero co2 emissions
Publication Date: 2023.12.21 SAIPEM SPA
  • US20230408192A1 patent drawing
  • US20230408192A1 patent drawing
  • US20230408192A1 patent drawing

AI summary

A system which integrates a power production system and an energy storage system represented by gas liquefaction systems is provided.