Pozzolan-Lime Cement Compositions for Pumpability and Strength

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Solution Overview

Problem

Cement compositions used in subterranean operations face challenges in maintaining low viscosity for extended periods while achieving sufficient compressive strength, often requiring costly additives that can cause compatibility issues.

Innovation Solution

The development of cement compositions comprising a pozzolan and lime, with specific selection based on surface area and particle size, and optional blending of pozzolans to control properties, allowing for set-delayed states that remain pumpable for extended periods without compromising compressive strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If cement composition uses low reactivity materials to maintain low viscosity for extended periods, then pumpability is improved, but compressive strength is insufficient

Engineering Contradiction:
ImprovepumpabilityVSAvoidcompressive strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent applies parameter changes by carefully controlling the surface area and particle size of pozzolan particles. By adjusting these physical parameters, the composition maintains low viscosity for extended pumpability while ensuring sufficient reactivity to develop adequate compressive strength after placement. The surface area is controlled within specific ranges to balance reaction rate with fluidity retention.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining pozzolan with lime in specific proportions. This composite approach allows the pozzolan to provide long-term strength development while the lime contributes to early strength and maintains workability. The synergistic interaction between these materials resolves the contradiction between low reactivity needs and strength requirements.

Inventive Principle:
Principle #40Composite materials

2Strength

If cement composition uses additives to enhance compressive strength, then strength is improved, but cost and compatibility issues increase

Engineering Contradiction:
Improvecompressive strengthVSAvoidcompositional complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent extracts the need for complex chemical additives by relying on the inherent properties of the pozzolan-lime system. By taking out the dependency on additional strength-enhancing additives and instead optimizing the base composition ratios and particle characteristics, the patent achieves sufficient strength with simpler, more compatible materials.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent applies self-service by allowing the pozzolan-lime composition to develop its own strength characteristics through proper formulation. The system self-regulates its reactivity and strength development based on the controlled particle properties and mixing ratios, eliminating the need for external additive interventions to achieve adequate compressive strength.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compositions maintain a pumpable fluid state for extended periods while achieving desirable compressive strength upon activation, reducing the need for costly additives and enhancing operational efficiency in subterranean applications.

Implementation Method 1

cement compositions comprising a pozzolan and lime

Methodology Applied
Scientific EffectPozzolanic reaction: Chemical Bonding

Data Source

PatentUS10781355B2Tunable control of pozzolan-lime cement compositions
Publication Date: 2020.09.22 HALLIBURTON ENERGY SERVICES INC
  • US10781355B2 patent drawing
  • US10781355B2 patent drawing

AI summary

A variety of cement compositions and methods of using cement compositions in subterranean formations. A method of formulating a cement composition may comprise: surface area of a group of pozzolans, wherein the smallest measured surface area of the group of pozzolans and the largest measured surface area of the group of pozzolans vary by about 50% or greater. The method may further comprise selecting one or more pozzolans from the group of pozzolans. The method may further comprise adding components comprising lime and water to the selected one or more pozzolans to form a cement composition.