Multilayer Hose PPA Inner Layer Chemical Resistance

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Solution Overview

Problem

Vehicle air conditioning system hoses face challenges in withstanding chemical aggression from new coolants like tetrafluoropropenes and PAG oils, requiring materials with optimal barrier properties and resistance to low and high temperatures, as well as high pressures, while being cost-effective.

Innovation Solution

A multilayer hose design featuring an inner layer of semiaromatic polyamide (PPA) with added elastomers, a second elastomeric layer, a reinforcement yarn layer, and an outer elastomeric covering layer, providing enhanced chemical resistance and mechanical strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional hose materials are used, then manufacturing cost is low, but chemical resistance to tetrafluoropropenes and PAG oils is insufficient

Engineering Contradiction:
Improvechemical resistanceVSAvoidmaterial cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs a multilayer composite structure where the inner layer uses PPA (polyphthalamide) resin specifically selected for its superior chemical resistance to tetrafluoropropenes and PAG oils, while outer layers use different materials optimized for mechanical strength and cost-effectiveness. This composite approach allows each layer to perform its specific function optimally, achieving high chemical resistance without making the entire hose prohibitively expensive.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention applies the local quality principle by using different materials for different layers of the hose. The inner layer that直接接触 the coolant and oil uses expensive but highly resistant PPA material, while outer layers that face less chemical exposure use more cost-effective materials. This localized material selection optimizes the balance between chemical resistance and manufacturing cost.

Inventive Principle:
Principle #3Local quality

2Reliability

If multilayer hose structure is implemented, then chemical resistance and barrier properties improve, but device complexity increases

Engineering Contradiction:
Improvebarrier propertiesVSAvoidhose structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The hose is segmented into multiple functional layers, each with specific properties. The inner layer provides chemical resistance and barrier properties using PPA resin, the intermediate layer provides mechanical reinforcement, and the outer layer provides protection and flexibility. This segmentation allows each layer to be optimized for its specific function while maintaining overall system reliability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

By using composite materials with different properties in each layer, the invention achieves superior overall performance. The PPA-based inner layer provides exceptional barrier properties against coolant and oil penetration, while combined with other materials it achieves the required mechanical strength and flexibility without excessive complexity.

Inventive Principle:
Principle #40Composite materials

3Reliability

If PPA resin is used in the inner layer, then chemical aggression resistance improves, but manufacturing precision requirements increase

Engineering Contradiction:
Improvechemical aggression resistanceVSAvoidmaterial composition control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent specifies precise parameter ranges for the PPA resin composition, including the content of repetitive units and molecular weight parameters. By controlling these parameters within defined ranges, the invention achieves consistent chemical resistance performance while managing manufacturing precision requirements. The specific parameter specifications guide manufacturers in achieving the desired performance without excessive complexity.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP2909030B1Multilayer hose for vehicle air conditioning system
Publication Date: 2020.09.09 SUMIRIKO ITAL SPA
  • EP2909030B1 patent drawingFigure 1~2
  • EP2909030B1 patent drawingFigure 3
  • EP2909030B1 patent drawingFigure 4

AI summary

A multilayer hose 7 is provided for use in vehicle air conditioning systems in particular for the transport of low environmental impact coolants such as fluoropropenes. According to the present invention the hose 7 comprises a first inner layer 8 comprising PPA or semiaromatic polyamide. The hose 7 furthermore comprises at least one second layer 9 comprising an elastomeric material.