PPO-Inhibiting Herbicide Control of Bryophyte Growth

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Solution Overview

Problem

Current methods for controlling unwanted cyanobacteria algae, mosses, liverworts, and other bryophytes, such as physical removal and chemical treatment with heavy metal herbicides, are inefficient and pose environmental risks due to high use rates and phytotoxicity.

Innovation Solution

The use of protoporphyrinogen oxidase enzyme-inhibiting herbicides, like carfentrazone ethyl, applied at low rates to control these plants, either alone or in combination with other herbicides, on various surfaces, effectively reducing their growth without causing significant harm to surrounding vegetation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If heavy metal herbicides (ferrous sulfate, copper sulfate) are used to control cyanobacteria algae, mosses, and bryophytes, then effective control is achieved, but high use rates cause phytotoxicity to turf grasses and accumulation of heavy metals in soil and environment

Engineering Contradiction:
Improvecontrol effectivenessVSAvoidphytotoxicity and heavy metal accumulation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameter of the herbicide from heavy metal salts to PPO-inhibiting compounds (e.g., carfentrazone-ethyl), which allows effective control of bryophytes at low use rates without causing phytotoxicity or heavy metal accumulation in the environment

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces persistent heavy metal herbicides with shorter-acting PPO-inhibiting compounds that achieve effective control without long-term environmental accumulation, effectively using a 'disposable' approach where the herbicide degrades after use rather than persisting in the ecosystem

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If physical removal methods are used to remove unwanted cyanobacteria algae, mosses, and bryophytes, then no chemical residues are left, but the process is time consuming and does not always result in permanent removal

Engineering Contradiction:
Improvechemical residuesVSAvoidtime consuming and temporary removal
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The patent replaces mechanical physical removal methods with chemical PPO-inhibiting herbicides that provide permanent control, substituting a mechanical system with a chemical system that achieves more durable results without the time-consuming nature of manual removal

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If high use rates of heavy metal herbicides are applied to ensure effective control, then control reliability is improved, but environmental accumulation and phytotoxicity increase

Engineering Contradiction:
Improvecontrol reliabilityVSAvoidherbicide use rate and environmental accumulation
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the chemical nature of the herbicide to PPO-inhibiting compounds with different dosing parameters, allowing effective control at low use rates rather than requiring high quantities of heavy metal salts, thereby reducing environmental accumulation while maintaining control reliability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for effective control of unwanted bryophytes at lower herbicide use rates, minimizing environmental impact and maintaining surface usability, as demonstrated by trials showing significant reduction in moss and algae growth compared to traditional methods.

Implementation Method 1

These herbicides are known as inhibitors of the enzyme protoporphyrinogen oxidase (commonly known as PPO-inhibitors), which cause disruption of cell membranes by inducing lipid peroxidation resulting in death to the plant

Methodology Applied
Scientific EffectLipid peroxidation: Oxidation

Data Source

PatentUS8119567B2Method for control of cyanobacterial algae, mosses, liverworts, hornworts and other bryophytes
Publication Date: 2012.02.21 FMC CORP
  • US8119567B2 patent drawing
  • US8119567B2 patent drawing

AI summary

Protoporphyrinogen oxidase enzyme-inhibiting herbicides are useful in a method for controlling unwanted cyanobacteria algae, mosses, liverworts, hornworts and other bryophytes. Of particular interest is the use of carfentrazone ethyl and certain metabolites thereof for control of unwanted cyanobacteria algae, mosses, liverworts, hornworts and other bryophytes.