PPS Nonwoven Fabric Crystallinity Multilayer Structure

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Poly(phenylene sulfide) (PPS) fiber nonwoven fabrics face challenges with poor dimensional stability against heat due to significant thermal shrinkage, low tensile strength, and complex production processes, which hinder their practical application in harsh environments.

Innovation Solution

A heat-resistant nonwoven fabric is developed using PPS fibers with crystallinity in the range of 25-50% by weight, forming a multilayer structure with high crystallinity layers and a low crystallinity intermediate layer, which reduces thermal shrinkage and maintains heat resistance, chemical resistance, and flame retardancy without the need for post-treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If PPS fiber nonwoven fabric is prepared by melt blowing with thin fibers to achieve excellent filtering performance, then filtering performance is improved, but tensile strength becomes low and dimensional stability against heat becomes poor

Engineering Contradiction:
Improvefiltering performanceVSAvoidtensile strength
Core Design Contradiction:
Measurement precisionVSStrength

Solution Approach 1:

The patent applies local quality by creating a multilayer structure where different layers have different crystallinity levels. The first and third layers have high crystallinity (40-50%) to provide strength and heat resistance, while the second layer has low crystallinity (10-30%) to maintain filtering performance. This spatial differentiation of material properties resolves the contradiction between strength and filtering performance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining PPS fibers with different crystallinity levels in a multilayer configuration. The high-crystallinity layers provide mechanical strength and dimensional stability, while the low-crystallinity layer provides filtering performance, creating a composite structure that achieves both requirements simultaneously.

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If PPS fiber nonwoven fabric is prepared by melt blowing with thin fibers to achieve excellent filtering performance, then filtering performance is improved, but dimensional stability against heat becomes poor

Engineering Contradiction:
Improvefiltering performanceVSAvoiddimensional stability against heat
Core Design Contradiction:
Measurement precisionVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by creating a multilayer structure where different layers have different crystallinity levels. The first and third layers have high crystallinity (40-50%) to provide strength and heat resistance, while the second layer has low crystallinity (10-30%) to maintain filtering performance. This spatial differentiation of material properties resolves the contradiction between strength and filtering performance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining PPS fibers with different crystallinity levels in a multilayer configuration. The high-crystallinity layers provide mechanical strength and dimensional stability, while the low-crystallinity layer provides filtering performance, creating a composite structure that achieves both requirements simultaneously.

Inventive Principle:
Principle #40Composite materials

3Stability of the object's composition

If post-treatment for dimensional stabilization against heat is applied to PPS fiber nonwoven fabric, then dimensional stability is improved, but production process becomes complicated and production efficiency is lowered

Engineering Contradiction:
Improvedimensional stability against heatVSAvoidproduction efficiency
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The patent applies preliminary action by incorporating dimensional stability into the fiber production process itself rather than applying post-treatment. The PPS fiber is spun with controlled crystallinity (40-50%) that inherently provides heat resistance, eliminating the need for subsequent heat treatment steps and maintaining high production efficiency.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses parameter changes by controlling the crystallinity of PPS fiber during the spinning process. By adjusting spinning parameters to achieve 40-50% crystallinity, the fiber gains inherent dimensional stability against heat, eliminating the need for post-treatment and maintaining production efficiency.

Inventive Principle:
Principle #35Parameter changes

4Temperature

If oxidation treatment is applied to PPS polymer to make it nonmelting, then heat resistance is improved, but the fiber becomes very brittle and production process becomes complicated

Engineering Contradiction:
Improveheat resistanceVSAvoidfiber brittleness
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The patent uses parameter changes by controlling the crystallinity of PPS fiber during the spinning process. By adjusting spinning parameters to achieve 40-50% crystallinity, the fiber gains inherent dimensional stability against heat, eliminating the need for post-treatment and maintaining production efficiency.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting nonwoven fabric exhibits excellent dimensional stability, heat resistance, and chemical resistance, with reduced thermal shrinkage and improved filtering and barrier performance, while simplifying the production process and reducing costs.

Implementation Method 1

30% by weight or more of the PPS fiber forming the nonwoven fabric has a crystallinity of 25 to 50%

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentEP2065500B1Heat-resistant non-woven fabric
Publication Date: 2017.06.07 ASAHI KASEI KOGYO KABUSHIKI KAISHA
  • EP2065500B1 patent drawingFigure 1
  • EP2065500B1 patent drawing
  • EP2065500B1 patent drawing

AI summary

The present invention provides a heat-resistant nonwoven fabric wherein the nonwoven fabric is formed from a poly(phenylene sulfide) fiber, and 30% by weight or more of the poly(phenylene sulfide) fiber has a crystallinity of 25 to 50%. Moreover, the properties of the heat-resistant nonwoven fabric can be further improved by making the nonwoven fabric have a multilayer structure in which layers composed of a poly(phenylene sulfide) filamentary fiber and layers composed of a poly(phenylene sulfide) fine fiber are stacked and integrated.