Pr-Garnet Ceramic Scintillator for High-Rate Photon Counting

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Solution Overview

Problem

Current photon-counting X-ray detectors face challenges in handling high counting rates, leading to signal overlap and difficulties in measuring correct X-ray photon energy, especially in applications like X-ray CT, which require a counting rate of 10^8 cps/mm^2 or more.

Innovation Solution

A ceramic scintillator formed of a garnet compound with specific composition and properties, including an absorption rate ratio and decay time constant, is developed to handle high counting rates, preventing signal pile-up and enabling accurate photon energy measurement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional scintillator materials are used in indirect type photon-counting detectors, then light emission is achieved, but the decay time constant is too long causing signal pile-up at high counting rates

Engineering Contradiction:
Improvedecay time constantVSAvoidmeasurement accuracy
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the material composition parameters of the scintillator by incorporating specific rare earth elements (Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, or Yb) into the Lu3-xRxAl5O12 compound, which fundamentally alters the decay time constant from conventional milliseconds to 17 nsec or less, enabling high-speed photon counting without signal pile-up

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite scintillator material by combining Lu3Al5O12 base compound with rare earth element dopants, achieving synergistic effects where the rare earth elements provide fast decay characteristics while the Lu3Al5O12 matrix maintains high light yield and X-ray absorption efficiency

Inventive Principle:
Principle #40Composite materials

2Speed

If semiconductor materials like CdTe are used in direct type photon-counting detectors, then high energy resolution is achieved, but the response speed is slow causing signal pile-up at high counting rates

Engineering Contradiction:
Improveresponse speedVSAvoidenergy resolution
Core Design Contradiction:
SpeedVSMeasurement precision

Solution Approach 1:

The patent introduces a scintillator material with ultra-fast decay (17 nsec or less) as an intermediary between X-ray photons and the photodetector, converting X-rays to light signals that can be processed at high speeds, thereby enabling fast response while maintaining energy measurement capability through the photodetector

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If photoelectron multiplier tubes are used in indirect type detectors, then high multiplication factor is achieved, but the device size becomes large making narrow pixel configuration difficult

Engineering Contradiction:
Improvepixel configuration flexibilityVSAvoiddetector size
Core Design Contradiction:
Ease of operationVSVolume of moving object

Solution Approach 1:

The patent replaces bulky, expensive photoelectron multiplier tubes with compact silicon photomultipliers (Si-PM), which are smaller, more affordable, and enable dense pixel configurations while maintaining high multiplication factors, thus reducing detector size and improving ease of operation

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ceramic scintillator achieves a decay time constant of 17 nsec or less, allowing for high counting rates without signal overlap, thus improving throughput and time resolution in X-ray detectors.

Implementation Method 1

a ceramic scintillator formed of a garnet compound containing Pr... an absorption rate at a wavelength of 320 [nm] relative to an absorption rate at a wavelength of 280 [nm] is 0.15 or less... achieves a decay time constant of 17 nsec or less

Methodology Applied
Scientific EffectScintillation: Scintillation

Data Source

PatentEP4703454A1Ceramic scintillator, photon counting type x-ray detector, and method for manufacturing ceramic scintillator
Publication Date: 2026.03.04 NITERRA MATERIALS CO LTD
  • EP4703454A1 patent drawingFigure 1(A)~1(C)
  • EP4703454A1 patent drawingFigure 2
  • EP4703454A1 patent drawingFigure 3

AI summary

In a ceramic scintillator formed of a garnet compound containing Pr, according to an embodiment, an absorption rate at a wavelength of 320 [nm] relative to an absorption rate at a wavelength of 280 [nm] is 0.15 or less.