Praseodymium Calibration Attachment for Optical Sensors

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Solution Overview

Problem

Existing fluorescence sensor calibration standards are prone to rapid aging, degradation under UV excitation, and lack temperature stability, making them unsuitable for long-term calibration and functional checks.

Innovation Solution

A calibration attachment using a praseodymium-doped body, which emits a stable fluorescence signal in the 250-500 nm range, resistant to aging, environmental influences, and UV excitation, is introduced.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If organic material standards (e.g., PMMA-based) are used for fluorescence calibration, then the calibration can be performed with solid standards, but the fluorescence signal degrades strongly under UV excitation

Engineering Contradiction:
Improvesolid standard handlingVSAvoidfluorescence signal stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent changes the material composition parameter by using inorganic materials (glass, ceramics, crystals) instead of organic materials (PMMA, plastics). This fundamental material parameter change makes the standard resistant to UV degradation while maintaining solid-state stability, directly resolving the contradiction between ease of operation and reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures, such as glass matrices doped with fluorescent inorganic compounds or ceramics with embedded fluorescent phases. These composite structures combine the mechanical stability of inorganic materials with controlled fluorescence properties, achieving both handling ease and signal stability.

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If liquid standards are used for fluorescence calibration, then the fluorescence intensity can be defined, but aging causes rapid change in fluorescence intensity after a few days

Engineering Contradiction:
Improvefluorescence intensity definitionVSAvoidcalibration stability over time
Core Design Contradiction:
Measurement precisionVSDuration of action of stationary object

Solution Approach 1:

The patent changes the physical state parameter from liquid to solid, and the compositional parameter from organic to inorganic materials. This transformation eliminates the aging problem inherent in liquid organic standards while preserving the ability to define and maintain precise fluorescence intensity values through controlled material composition.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates long-lasting calibration standards that replace short-lived liquid standards. The inorganic solid standards have dramatically extended service lives (years instead of days), eliminating the need for frequent replacement and recalibration, thus improving duration of action.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Ease of operation

If conventional solid standards are used, then handling is simplified, but temperature stability is not fulfilled

Engineering Contradiction:
Improvestandard handlingVSAvoidtemperature stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent uses inorganic composite materials (glass-ceramics, doped ceramics, crystalline materials) that inherently possess both mechanical stability for easy handling and thermal stability for temperature independence. The inorganic matrix structure provides resistance to thermal expansion and phase changes, maintaining fluorescence properties across temperature variations.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material composition parameter to inorganic substances with high melting points and low thermal expansion coefficients. This parameter change confers temperature stability while maintaining the solid-state form factor for ease of handling, resolving the contradiction between operational convenience and compositional stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The praseodymium-based calibration attachment provides a stable fluorescence signal that remains consistent under multi-day irradiation, temperature changes, humidity variations, and long-term storage, enabling universal and complete calibration of optical sensors.

Implementation Method 1

the body, after excitation with the transmitted light, in particular by absorption of the transmitted light, emits light of a different, in particular longer, wavelength

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 2

after excitation with the transmitted light, in particular by absorption of the transmitted light

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentUS20250044229A1Calibration standard, sensor arrangement and use
Publication Date: 2025.02.06 ENDRESS HAUSER CONDUCTA GMBH CO KG
  • US20250044229A1 patent drawing
  • US20250044229A1 patent drawing

AI summary

The invention discloses a calibration attachment for adjustment, calibration and/or for carrying out a functional check of an optical sensor, which is configured for measuring at least one measurement variable in a medium using light. The sensor is configured for emitting emission light of at least a wavelength in the range of 200-450 nm, comprising a housing and a body arranged in the housing wherein the body comprises praseodymium, and after excitation with the emission light, the body emits light with a longer wavelength. The invention also discloses a sensor arrangement comprising such a calibration attachment, and a use of same.