Pre-treatment Composition for Inkjet Printing

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Solution Overview

Problem

Current inkjet printing technologies face challenges in achieving high-quality, durable images with stable pre-treatment compositions that enhance optical density and resistance to smudging and light exposure, particularly on slow-absorbing media.

Innovation Solution

A pre-treatment composition comprising a liquid vehicle, a polyvalent metal salt as a fixing agent, and a latex resin with an acid number of less than 20 is applied to the recording medium, followed by an ink composition, which causes effective immobilization of colorants on the surface, improving image quality and durability while allowing high-speed printing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional pre-treatment compositions are used, then printing speed can be maintained at high levels, but image quality attributes such as optical density and durability are insufficient

Engineering Contradiction:
Improveimage qualityVSAvoidprinting speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent modifies the chemical parameters of the pre-treatment composition by incorporating specific metal salts (alumina, silica, titania) with controlled particle sizes (0.1-10 μm) and concentrations (1-50 wt%), along with specific polymers and surfactants. These parameter changes enable the composition to achieve both high optical density and durability while maintaining compatibility with high-speed printing processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite pre-treatment composition combining multiple functional components: metal oxides (alumina, silica, titania), polymers (acrylic, vinyl acetate, polyester), surfactants, and wetting agents. This composite formulation synergistically improves image quality attributes including optical density, chroma, and durability while maintaining the ability to print at high speeds.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If pre-treatment composition is applied to enhance optical density and durability, then image quality improves, but the composition stability and reliability decrease

Engineering Contradiction:
Improveoptical densityVSAvoidcomposition stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent carefully controls the pH value (7-11), metal ion concentration (1-50 wt%), and polymer composition to ensure composition stability. The specific parameter ranges prevent unwanted chemical reactions while maintaining optical density enhancement, thereby improving both image quality and composition reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses surfactants and wetting agents as intermediary substances that mediate between the metal oxide particles and the polymer matrix, ensuring stable composition while maintaining optical properties. These intermediaries prevent aggregation and ensure uniform distribution, improving both optical density and composition stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If pre-treatment composition is formulated to improve smudge resistance and light fastness, then image durability increases, but the complexity of formulation and application increases

Engineering Contradiction:
Improvesmudge resistanceVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent develops a multi-functional pre-treatment composition where metal oxides provide both optical density enhancement and smudge resistance, while polymers contribute to both durability and light fastness. The surfactants simultaneously improve wetting and prevent smudging. This multi-functionality reduces the need for separate additives, simplifying the overall formulation while maintaining high durability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention optimizes the concentration ranges of each component (metal oxides: 1-50 wt%, polymers: 1-50 wt%, surfactants: 0.1-5 wt%) to achieve the desired smudge resistance and light fastness with minimal formulation complexity. The specific parameter ranges ensure stable performance without requiring overly complex formulation processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in enhanced image quality attributes such as optical density, chroma, and durability, with improved smudge resistance and light fastness, and is particularly effective on slow-absorbing media like coated offset paper, maintaining stability over time.

Implementation Method 1

a pre-treatment composition that includes a liquid vehicle, a polyvalent metal salt as a fixing agent and a latex resin having an acid number of less than 20

Methodology Applied
Scientific EffectChemical interaction/precipitation: Precipitation

Implementation Method 2

a latex resin having an acid number of less than 20

Methodology Applied
Scientific EffectAcid-base interaction: Chemical Bonding

Data Source

PatentUS8851652B2Pre-treatment composition
Publication Date: 2014.10.07 HEWLETT PACKARD DEVELOPMENT COMPANY LP
  • US8851652B2 patent drawing
  • US8851652B2 patent drawing

AI summary

Pre-treatment composition and printing method using such pre-treatment composition are disclosed. A disclosed example of the pre-treatment composition includes a liquid vehicle, a polyvalent metal salt as fixing agent, and a latex resin having an acid number of less than 20.