Iron-Based Prealloy Powder Composition for Strength and Moldability

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Solution Overview

Problem

Iron-based prealloy powders face challenges in achieving improved strength and processability, particularly in sinter-forged automotive components like synchronizer hubs and connecting rods, as increased alloy content reduces moldability and strength, and conventional sinter-forged products require high sintering temperatures or long times.

Innovation Solution

An iron-based prealloy powder composition with specific ranges of Cu, Mo, and Mn, along with a diffusion-bonded powder process where Cu is bonded to the surface of the prealloy powder, and an alloy powder mixed with carbon and sulfur, to enhance strength and processability without heat treatment, ensuring a martensite area ratio less than 5% and yield strength of 500 MPa or more.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the content of alloy elements (Cu, Mo, Mn) is increased to improve strength, then the strength of sinter-forged members is improved, but the moldability is reduced

Engineering Contradiction:
Improvestrength of sinter-forged membersVSAvoidmoldability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The invention optimizes the specific parameter ranges of alloy element contents (Cu: 0.5-5.0 wt%, Mo: 0.1-0.5 wt%, Mn: 0.05-0.4 wt%) and their relational equations to achieve the best balance between strength and moldability. By precisely controlling these parameters and their relationships, the invention maximizes strength improvement while maintaining adequate moldability for manufacturing.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite powder system combining prealloyed iron-based powder with specific alloy elements (Cu, Mo, Mn) and additives. This composite structure allows synergistic effects where each element contributes specific properties: Cu for strength, Mo for hardenability and precipitate formation, and Mn for microstructure control, achieving superior overall performance while maintaining processability.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional sintering methods are used with pure iron powder mixed with copper and carbon powders, then the process is simple, but high sintering temperature or long sintering time is required to achieve sufficient alloy diffusion

Engineering Contradiction:
Improveprocess complexityVSAvoidsintering temperature and time
Core Design Contradiction:
Device complexityVSUse of energy by stationary object

Solution Approach 1:

The invention applies preliminary action by pre-alloying the iron-based powder with copper and molybdenum elements before the sintering process. This pre-alloying ensures that alloy elements are already distributed within the iron matrix, eliminating the need for high-temperature or long-duration sintering to achieve diffusion. The preliminary preparation of the powder composition enables effective alloying at lower sintering temperatures and shorter times.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If prealloy powder is used to achieve sufficient alloy diffusion at lower sintering temperature, then the sintering process is more efficient, but the contribution to strength improvement is lowered when alloy content is increased

Engineering Contradiction:
Improvesintering efficiencyVSAvoidstrength improvement contribution
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The invention changes the parameters of alloy element composition and their relational equations to optimize the balance between sintering efficiency and strength improvement. By controlling the specific ranges and relationships of Cu, Mo, and Mn contents, the invention ensures that prealloyed powder achieves both efficient diffusion at lower temperatures and maximum strength contribution from the alloy elements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite powder system with multiple alloy elements (Cu, Mo, Mn) and additives that work synergistically. This composite structure allows the prealloyed powder to maintain high sintering efficiency while the combination of elements provides cumulative strength improvement, overcoming the limitation of single-element prealloyed systems.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves improved strength and processability in sinter-forged members, such as automotive connecting rods, with uniform Cu distribution, finer precipitates, and suppressed martensite formation, allowing for high-strength, cost-effective manufacturing at lower sintering temperatures and reduced process complexity.

Implementation Method 1

an iron-based diffusion-bonded powder according to an embodiment of the present disclosure includes a Cu powder at a content of less than 5 wt % bonded to the surface of an iron-based prealloy powder

Methodology Applied
Scientific EffectDiffusion bonding: Diffusion Welding

Data Source

PatentUS11542579B2Iron-based prealloy powder, iron-based diffusion-bonded powder, and iron-based alloy powder for powder metallurgy using the same
Publication Date: 2023.01.03 HYUNDAI MOTOR CO LTD
  • US11542579B2 patent drawing
  • US11542579B2 patent drawing

AI summary

The present disclosure relates to an iron-based prealloy powder having excellent strength and processability, and an iron-based alloy powder for powder metallurgy and a sinter-forged member using the same. The iron-based prealloy powder for powder metallurgy according to an embodiment of the present disclosure includes 0.5 to 5.0 wt % of Cu, 0.1 to 0.5 wt % of Mo, and a balance of Fe and other inevitable impurities. A Cu content (Cu %) and a Mo content (Mo %) satisfy the following Relational Equation (1):0.3×Cu %+3×Mo %≤2.7  (1).