Precipitated Particles for Wellbore Fluid Density and Rheology

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Solution Overview

Problem

Conventional weighting particles in wellbore circulation fluids, such as ground minerals, have limited shape and size variability, leading to suboptimal densification, rheological performance, and fluid loss control, and are often compromised by impurities and quality issues, making it difficult to tailor fluid properties for specific subterranean operations.

Innovation Solution

Precipitated particles with tailored morphology and size are produced through controlled precipitation conditions, including adjusting temperature, reactant concentration, and the presence of carbohydrate-based materials or electric fields, without using polymeric dispersants, to enhance density, rheology, and fluid loss control, and can be used to improve the properties of ground mineral particles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If ground mineral particles are used as weighting particles, then the fluid density can be increased, but the particle shape and size variability is limited, leading to suboptimal rheological performance and fluid loss control

Engineering Contradiction:
Improvefluid densityVSAvoidparticle shape and size variability
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent applies parameter changes by controlling precipitation conditions (temperature, pH, reactant concentration, addition rate) to produce particles with tailored shapes and sizes. This transforms the fixed properties of ground minerals into variable, optimized properties that simultaneously achieve desired density, rheology, and fluid loss control.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite particles by precipitating one mineral onto seed particles of another mineral or material. This allows combining the high density of minerals like barite with the controlled morphology of precipitated structures, achieving both densification and optimized rheological performance.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If conventional weighting particles are used, then densification is achieved, but the particles often contain impurities and quality issues that compromise fluid performance

Engineering Contradiction:
Improvefluid densityVSAvoidfluid performance consistency
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent extracts only the essential function of weighting particles (providing density) while eliminating the harmful impurities associated with ground minerals. By precipitating pure mineral phases under controlled conditions, the invention achieves reliable, consistent fluid performance without the quality variability of commercial ground minerals.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses readily available, inexpensive reactants (such as calcium carbonate precursors or barium chloride and sulfate) to produce high-purity weighting particles. This replaces expensive, variable-quality ground minerals with cost-effective, consistently pure precipitated particles.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Quantity of substance

If ground mineral particles are used, then weighting function is provided, but it is difficult to tailor fluid properties for specific subterranean operations

Engineering Contradiction:
Improveweighting functionVSAvoidfluid property tailoring
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent introduces dynamics by making particle properties (shape, size, composition, surface characteristics) adjustable through controllable precipitation parameters. This allows the fluid properties to be dynamically tailored to specific operational requirements, whether for drilling, cementing, or stimulation, rather than being fixed by the properties of ground minerals.

Inventive Principle:
Principle #15Dynamics

4Manufacturing precision

If polymeric dispersants are used during precipitation, then particle formation is controlled, but environmental impact and costs increase

Engineering Contradiction:
Improveparticle morphology controlVSAvoidenvironmental impact and cost
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent converts the typically harmful or costly role of polymeric dispersants into a beneficial, environmentally friendly process by using simple carbohydrate-based materials (sugars, sugar alcohols, sugar acids) as precipitation modifiers. These natural substances provide effective particle morphology control while being biodegradable, non-toxic, and inexpensive, eliminating the environmental and cost concerns associated with synthetic polymers.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of precipitated particles results in wellbore circulation fluids with improved sag resistance, increased viscosity, and enhanced fluid loss control, while reducing environmental impact and costs, and allows for the recycling and upgrading of lower-quality mineral sources.

Implementation Method 1

forming the precipitated particles from a reaction mixture under the precipitation conditions

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 2

applying an electric field to the reaction mixture

Methodology Applied
Scientific EffectElectric field: Electric Field

Data Source

PatentUS10202531B2Wellbore methods employing precipitated particles
Publication Date: 2019.02.12 HALLIBURTON ENERGY SERVICES INC
  • US10202531B2 patent drawing
  • US10202531B2 patent drawing
  • US10202531B2 patent drawing

AI summary

Precipitated particles may be formed under conditions that provide a particle morphology suitable for conveying a desired set of properties to a wellbore circulation fluid. Methods for using precipitated particles in a wellbore may comprise: selecting precipitation conditions for producing precipitated particles that are substantially non-spherical in shape, are about 1 micron or under in size, or any combination thereof; forming the precipitated particles from a reaction mixture under the precipitation conditions without using a polymeric dispersant; and introducing a wellbore circulation fluid comprising a plurality of the precipitated particles into a wellbore penetrating a subterranean formation. The precipitation conditions may include one or more of modulating various reaction conditions, applying an electric field to the reaction mixture, or including a carbohydrate-based material in the reaction mixture.