Non-Volatile Precursor Compounds for Long-Lasting Floral Odor

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Solution Overview

Problem

Existing perfumes and perfumed articles have limited longevity due to the high volatility of their fragrance components, resulting in a short-lasting odor perception, particularly for fresh green, floral, and fruity notes.

Innovation Solution

The use of specific compounds of formula (I), which are non-volatile and essentially odorless, that slowly generate α,β-unsaturated aldehydes or ketones and thiols over time, providing a long-lasting floral and fruity odor when applied to surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of moving object

If volatile fragrance compounds are used to provide fresh green, floral, and fruity notes, then the desired odor character is achieved, but the duration of odor perception is limited

Engineering Contradiction:
Improveduration of odor perceptionVSAvoidhigh volatility of fragrance
Core Design Contradiction:
Duration of action of moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent applies preliminary action by incorporating non-volatile precursor compounds (sulfones, sulfonates, or sulfoxones) into the perfume composition before application. These precursors are deposited onto the skin in advance and then slowly convert into the desired volatile fragrance compounds over time, providing a long-lasting odor effect without the initial volatility problem

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses non-volatile sulfur-containing compounds as intermediary substances that serve as precursors. These intermediaries are applied to the skin and gradually transform into the actual fragrance molecules through oxidation and hydrolysis reactions, mediating between the need for long-lasting presence and the need for volatile odor release

Inventive Principle:
Principle #24Intermediary (Mediator)

2Duration of action of moving object

If non-volatile compounds are used to extend odor duration, then the longevity is improved, but the compounds are essentially odorless without slow generation of fragrance

Engineering Contradiction:
Improvelong-lasting odorVSAvoidessentially odorless nature of compounds
Core Design Contradiction:
Duration of action of moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent applies self-service by designing precursor compounds that automatically transform into fragrance molecules through reactions with components naturally present on the skin (such as enzymes, moisture, or oxygen). The compounds self-generate the desired odor without requiring external triggers or additional ingredients, providing both longevity and fragrance character

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent utilizes parameter changes by controlling the chemical transformation of precursor compounds through changes in molecular structure, oxidation state, and hydrolysis rate. The precursors are designed with specific functional groups that undergo controlled chemical changes over time, transitioning from non-volatile, odorless states to volatile, fragrant states, thereby achieving both long duration and desired odor character

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compounds effectively impart a long-lasting, substantive odor to surfaces such as hard surfaces, fabric, skin, or hair, enhancing the deposition of perfume and extending the duration of floral and fruity odor perception.

Implementation Method 1

specific compounds of formula (I), which are non-volatile and essentially odorless, that slowly generate α,β-unsaturated aldehydes or ketones and thiols over time

Methodology Applied
Scientific EffectChemical decomposition: Decomposition (biological)

Data Source

PatentUS12291689B2Compounds for providing a long-lasting floral and fruity odor
Publication Date: 2025.05.06 FIRMENICH SA
  • US12291689B2 patent drawing
  • US12291689B2 patent drawing
  • US12291689B2 patent drawing

AI summary

Described herein are compounds of formula (I) that are able to provide a long-lasting or substantive odor, in particular floral and/or fruity odor, to the environment. Also described herein is a method of imparting a long-lasting odor, in particular a fresh green, floral and/or fruity odor, to surfaces, such as hard surfaces, fabric, skin or hair. Also described herein are a method of using said compounds in perfumery and perfuming compositions or perfumed articles including the compounds described herein.