Precursor Deposition and Curing for Repeatable Gap-Fill Layers

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Solution Overview

Problem

Existing vapor phase deposition processes face challenges in achieving repeatability, layer quality, and process speed when depositing materials, particularly in filling recesses, trenches, or gaps in substrates.

Innovation Solution

A system comprising a reaction chamber, precursor source, gas injection system, and curing unit, with controlled temperature zones and various curing methods such as radio frequency, infrared, UV, microwave, and remote plasma sources, is used to deposit and cure precursors on a substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional vapor phase deposition processes are used, then deposition can be performed, but repeatability, layer quality, and process speed are compromised due to tradeoffs

Engineering Contradiction:
Improvedeposition repeatabilityVSAvoidprocess speed
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The deposition process is divided into separate sequential steps: precursor introduction, condensation/deposition, and curing. This segmentation allows each step to be optimized independently, improving repeatability without sacrificing overall process speed. The precursor is introduced, allowed to condense on the substrate, then cured in a separate step to complete the deposition cycle.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The process employs periodic cycling between precursor introduction and curing steps. By repeatedly introducing precursor material and then curing it in alternating cycles, the system achieves consistent layer buildup with high repeatability while maintaining efficient process throughput through the periodic nature of the deposition-curing sequence.

Inventive Principle:
Principle #19Periodic action

2Manufacturing precision

If conventional vapor phase deposition is used, then material can be deposited, but layer quality suffers when filling narrow gaps and recesses

Engineering Contradiction:
Improvelayer qualityVSAvoiddifficulty of filling narrow gaps
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The precursor is introduced and allowed to condense on the substrate surface before the curing step. This preliminary condensation action ensures that precursor material is properly positioned and distributed in narrow gaps and recesses before the curing process locks it into place, improving layer quality in difficult-to-reach areas.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The process utilizes phase transition of the precursor from vapor phase to condensed phase on the substrate surface. This phase change allows the precursor to naturally flow into and fill narrow gaps and recesses uniformly, then the curing step stabilizes the material in this improved distribution, achieving high manufacturing precision.

Inventive Principle:
Principle #36Phase transitions

3Productivity

If higher process speed is achieved, then productivity improves, but deposition repeatability and layer quality deteriorate

Engineering Contradiction:
Improveprocess speedVSAvoidlayer quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The curing unit operates continuously or in overlapping fashion with the precursor introduction cycles. While precursor is being introduced in one area, curing can proceed in another area or simultaneously, maintaining continuous useful action. This eliminates idle time between deposition and curing steps, improving productivity without sacrificing layer quality.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system enables repeatable and precise deposition of thin layers with controlled thickness, allowing for efficient filling of narrow gaps and improving layer quality while maintaining process efficiency.

Implementation Method 1

The precursor source comprises a precursor source heater

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

The gas injection system heater is arranged for heating the gas injection system

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

the showerhead injector comprises a showerhead injector heater

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

The reaction chamber comprises a substrate support which in turn comprises a substrate cooling unit

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 5

The system further comprises a radio frequency power source which is arranged for generating a radio frequency power waveform

Methodology Applied
Scientific EffectRadio frequency generation: Electromagnetic Induction

Implementation Method 6

The curing unit comprises an infrared source

Methodology Applied
Scientific EffectInfrared radiation: Infrared Radiation

Implementation Method 7

The curing unit comprises a UV source

Methodology Applied
Scientific EffectUltraviolet curing: Photopolymerisation

Implementation Method 8

The curing unit comprises a microwave source

Methodology Applied
Scientific EffectMicrowave heating: Microwave Radiation

Implementation Method 9

The curing unit comprises a remote plasma source

Methodology Applied
Scientific EffectPlasma generation: Plasma

Data Source

PatentUS12584221B2Methods and systems for depositing a layer
Publication Date: 2026.03.24 ASM IP HLDG BV
  • US12584221B2 patent drawing
  • US12584221B2 patent drawing
  • US12584221B2 patent drawing

AI summary

Systems for depositing materials and related methods are described. The systems allow condensing or depositing a precursor on a substrate, and then curing condensed or deposited precursor to form a layer.