Preliminary Charge Transport Layer for OLED Manufacturing

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Solution Overview

Problem

The existing methods for manufacturing organic light emitting display devices often result in degradation of luminescence characteristics due to the use of electrodes as etching masks for charge transport layers, leading to damage and suboptimal performance.

Innovation Solution

A method involving the formation of a preliminary charge transport layer using processes like slit coating or spin coating, followed by selective etching with solutions like water, acetone, and anisole, and application via printing processes, which allows for the formation of a charge transport layer before the second electrode, improving electrical contact and encapsulation efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If electrodes are used as etching masks for charge transport layers, then the manufacturing process is simplified, but luminescence characteristics are degraded due to electrode damage

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidluminescence characteristics
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The charge transport layer formation process is segmented into two distinct stages: first forming a preliminary charge transport layer using the electrode as mask, then selectively etching this preliminary layer to create the final charge transport layer. This segmentation allows the electrode to serve its masking function without directly damaging the luminescence layer, as the etching is controlled to remove only the preliminary layer in specific regions.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A preliminary charge transport layer is formed in advance before the selective etching process. This preliminary layer acts as a sacrificial mask that protects the luminescence layer during etching, while still allowing the electrode to function as the primary mask. The preliminary action of forming this protective layer eliminates the direct harmful interaction between the electrode and luminescence characteristics.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If the charge transport layer is formed after the second electrode, then the manufacturing sequence is simplified, but electrical contact efficiency and encapsulation are reduced

Engineering Contradiction:
Improvemanufacturing sequence efficiencyVSAvoidelectrical contact efficiency
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The charge transport layer is formed preliminarily before the second electrode is completely finalized, allowing subsequent encapsulation processes to effectively seal the lower substrate. This preliminary formation enables better electrical contact efficiency while maintaining manufacturing productivity through the selective etching approach that defines precise contact regions.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The selective etching process creates local variations in the charge transport layer, forming specific contact regions with enhanced electrical properties where needed. This local quality modification improves electrical contact efficiency at critical interfaces while maintaining the overall manufacturing sequence efficiency through controlled, localized processing.

Inventive Principle:
Principle #3Local quality

3Area of stationary object

If the preliminary charge transport layer covers the entire first electrode and pixel defining layer, then complete coverage is achieved, but selective etching complexity increases

Engineering Contradiction:
Improvecharge transport layer coverage areaVSAvoidselective etching process complexity
Core Design Contradiction:
Area of stationary objectVSDevice complexity

Solution Approach 1:

The preliminary charge transport layer serves a dual function: it provides complete coverage for protection and acts as its own etching mask. The selective etching process utilizes the layer's own material properties and the electrode geometry to define the final pattern, eliminating the need for separate complex masking processes and reducing overall device complexity despite the initial complete coverage.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances luminescence characteristics and extends the lifespan of organic light emitting display devices by improving electrical contact efficiency and encapsulating the lower substrate effectively.

Implementation Method 1

The preliminary charge transport layer may be partially etched by an etching solution including at least one of water, acetone and anisole

Methodology Applied
Scientific EffectChemical etching:

Implementation Method 2

applying an inert gas on the lower substrate to remove the etching solution remaining on the lower substrate

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS9196834B2Method of manufacturing an organic light emitting structure and method of manufacturing an organic light emitting display device
Publication Date: 2015.11.24 SAMSUNG DISPLAY CO LTD
  • US9196834B2 patent drawing
  • US9196834B2 patent drawing
  • US9196834B2 patent drawing

AI summary

A method of manufacturing an organic light emitting structure is provided as follows. A first electrode is formed on a lower substrate. A pixel defining layer is formed adjacent to the first electrode on the lower substrate. A preliminary charge transport layer is formed on the first electrode and the pixel defining layer. An organic light emitting layer is formed on the preliminary charge transport layer. The preliminary charge transport layer is selectively etched to form a charge transport layer. A second electrode is formed on the organic light emitting layer.