Premixed Host Materials for OLED Evaporation

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Solution Overview

Problem

Current organic light emitting devices (OLEDs) face challenges in achieving balanced charge transport and stability, leading to variations in device voltage, efficiency, and lifetime when using individual host materials, and there is a need for a consistent method to evaporate multiple host materials simultaneously while maintaining performance.

Innovation Solution

A combination of triphenylene-dibenzoselenophene, triphenylene-dibenzothiophene, or triphenylene-dibenzofuran materials with an indolocarbazole derivative is used as a host material mixture, which can be co-evaporated or premix-evaporated to enhance charge balance and stability, and the mixture is evaporated from a single source to ensure uniform deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If individual host materials are used in OLEDs, then device fabrication is simpler, but charge transport balance and device stability deteriorate

Engineering Contradiction:
Improvefabrication complexityVSAvoidcharge transport balance and device stability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent uses composite host materials consisting of multiple organic compounds (e.g., mCP, TCTA, TAPC) combined in specific ratios to achieve balanced charge transport and improved device stability. The composite host system allows synergistic effects where different materials contribute complementary properties, resolving the contradiction between simple fabrication and reliable performance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If multiple host materials are evaporated simultaneously from separate sources, then charge balance improves, but manufacturing complexity increases

Engineering Contradiction:
Improvecharge balanceVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges multiple host materials into a single premixed composition that is deposited from one evaporation source. This approach maintains the charge balance benefits of multiple materials while simplifying manufacturing by eliminating the need for multiple separate deposition sources and complex synchronization control.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The host materials are pre-mixed in predetermined ratios before deposition, establishing the optimal composition in advance. This preliminary action ensures consistent charge balance performance while simplifying the deposition process, as the mixture requires only single-source evaporation without real-time ratio control.

Inventive Principle:
Principle #10Preliminary action

3Adaptability or versatility

If host materials with different evaporation characteristics are used, then material selection flexibility increases, but deposition uniformity deteriorates

Engineering Contradiction:
Improvematerial selection flexibilityVSAvoiddeposition uniformity
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent selects host materials whose evaporation characteristics (vapor pressure, evaporation rate) are within a compatible range, specifically where the ratio of their evaporation rates remains relatively constant across the operating temperature range. This parameter matching ensures that premixed materials deposit uniformly from a single source while still allowing flexibility in material selection.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This combination results in OLEDs with improved luminous efficiency, lower operating voltage, and extended lifetime, demonstrating synergistic effects that surpass the performance of devices using individual host materials, with consistent evaporation ensuring uniform film deposition.

Implementation Method 1

the mixture is evaporated from a single source to ensure uniform deposition

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

co-evaporated or premix evaporated to provide devices with improved lifetime and efficiency

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentEP2564438B1Depositing premixed materials
Publication Date: 2016.10.19 UNIVERSAL DISPLAY CORP
  • EP2564438B1 patent drawingFigure 1
  • EP2564438B1 patent drawingFigure 2
  • EP2564438B1 patent drawing

AI summary

A combination of host materials suitable for co-evaporation or premix evaporation, and devices containing the combination of host materials are provided. The combination of host materials provides improved lifetime and efficiency. A method for fabricating devices containing the host material combination is also provided.