Partially Impregnated Prepreg Tapes for Void-Free Composite Laminates

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Solution Overview

Problem

The manufacturing of thick composite parts often results in porosity (voids) due to entrapped volatiles, which compromises mechanical properties and is costly to address with autoclaving, and existing vacuum bag processes produce inferior quality laminates with voids.

Innovation Solution

The use of partially impregnated prepregs with a resin content of 25-50% by weight, which allows for resin infusion during heating in a Vacuum Bag Only process, and a method to slit these prepregs into narrow-width tapes for automated placement without jamming, using a nonwoven veil and binder to facilitate air evacuation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional fully impregnated prepregs are used in vacuum bag processing, then production cost is reduced, but voids form in the composite laminate due to entrapped volatiles

Engineering Contradiction:
Improveproduction costVSAvoidvoid content in laminate
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The prepreg is designed with non-uniform resin distribution: the resin-rich surface layer (5-20 mils thick) provides volatile entrapment and evacuation pathways, while the underlying fiber-rich region ensures structural integrity. This local differentiation allows the same material to simultaneously enable void-free curing and maintain mechanical properties.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The resin-rich surface layer is pre-formed on the prepreg before lamination, creating built-in volatile collection zones and evacuation pathways that are already in place before the curing process begins. This preliminary preparation eliminates the need for post-curing void repair and enables direct vacuum bag processing.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If resin content in prepreg is reduced to enable void-free curing, then void content decreases, but handling and automated placement become difficult due to excessive tackiness

Engineering Contradiction:
Improvevoid-free laminate qualityVSAvoidhandling and placement ease
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The prepreg structure separates the resin-rich surface layer (providing volatile management) from the fiber-rich interior (maintaining handling properties). The resin content in the bulk is kept low (25-50% by weight) to reduce tackiness, while the surface layer thickness (5-20 mils) is optimized to provide sufficient volatile entrapment without excessive surface stickiness.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention creates a composite structure within the prepreg itself: a resin-rich polymer phase on the surface and a fiber-rich reinforcement phase in the interior. This internal composite architecture allows each region to perform its specialized function: the resin-rich layer manages volatiles while the fiber-rich core maintains structural integrity and handling characteristics.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of void-free composite laminates suitable for automated fiber placement, maintaining mechanical integrity while reducing production costs and avoiding the limitations of autoclaving.

Implementation Method 1

a) a first layer of fibers is impregnated with a resin composition to form a fibrous laminate; b) the fibrous laminate is heated to cure the resin composition

Methodology Applied
Scientific EffectCuring: Phase Change

Implementation Method 2

enclosing the stack of prepreg plies in a vacuum envelope... withdrawing air from the vacuum envelope to create a vacuum pressure sufficient for consolidating the stack of prepreg plies

Methodology Applied
Scientific EffectVacuum: Vacuum

Data Source

PatentEP3898207B1Automated placement of prepreg tapes to form composite parts
Publication Date: 2023.02.22 CYTEC IND INC
  • EP3898207B1 patent drawingFigure 1A~2B
  • EP3898207B1 patent drawingFigure 3~5
  • EP3898207B1 patent drawingFigure 6~7

AI summary

Prepreg tapes suitable for automated placement process are formed by slitting a sheet of partially impregnated prepreg. The partially impregnated prepreg (13) is composed of unidirectional fiber tows partially embedded in a resin layer and has a continuous resin surface only on one side. In some embodiments, one or two nonwoven veil(s) is/are incorporated into the partially impregnated prepreg.