Pre-processing Fluid Wettability and Defoamability

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Solution Overview

Problem

The image density of images formed on plain paper using aqueous pigment ink is low, and existing pre-processing fluids suffer from uneven coloring due to low wettability and defoamability issues.

Innovation Solution

A pre-processing fluid containing water, a water-soluble organic solvent, a water-soluble flocculant, and specific compounds such as C6F13—CH2CH2O(CH2CH2O)nH and HOR1R3C—(CH2)m—CR2R4OH, which improve wettability and defoamability, thereby enhancing image density and reducing uneven coloring.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a pre-processing fluid is applied before aqueous pigment ink discharge, then image density is improved, but uneven coloring occurs due to low wettability and defoamability

Engineering Contradiction:
Improveimage densityVSAvoidcolor uniformity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the pre-processing fluid by incorporating specific compounds: a fluorine-containing compound (C6F13—CH2CH2O(CH2CH2O)nH) to enhance wettability and reduce surface tension, and a silane-based compound (HOR1R3C—(CH2)m—CR2R4OH) to improve defoamability. These parameter changes resolve the contradiction by enabling both high image density and uniform color distribution.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite pre-processing fluid system combining multiple functional components: water, water-soluble organic solvent, water-soluble flocculant, fluorine-containing compound, and silane-based compound. This composite formulation synergistically addresses both wettability and defoamability issues, achieving improved image density while preventing uneven coloring.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If conventional surfactants are used to improve wettability, then fluid spreading is enhanced, but defoamability deteriorates

Engineering Contradiction:
ImprovewettabilityVSAvoiddefoamability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent introduces a silane-based compound (HOR1R3C—(CH2)m—CR2R4OH) as an intermediary substance that specifically targets foam stabilization. This compound acts as a mediator between the wetting agents and the fluid system, controlling foam formation without interfering with the wettability-enhancing function of the fluorine-containing compound.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the surface chemical parameters by adding the silane-based compound with specific structural characteristics (R1-R4 being alkyl or aryl groups, m being 1-6). This parameter change specifically addresses the defoamability issue while maintaining the wettability improvements achieved by other components.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If N-alkyl-2-pyrolidone and fluorine-containing surfactant are used to improve wettability and defoamability, then fluid performance is enhanced, but uneven coloring still occurs

Engineering Contradiction:
Improvewettability and defoamabilityVSAvoidcolor uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent further refines the chemical parameters by selecting specific compounds within established classes: fluorine-containing compounds with n=1-40 for optimal wettability, and silane-based compounds with controlled chain lengths (m=1-6) and substituent groups for enhanced defoamability and color uniformity. These precise parameter adjustments eliminate uneven coloring while maintaining improved wettability and defoamability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The pre-processing fluid achieves high image density on plain paper while minimizing uneven coloring and improving defoamability, ensuring even application and effective inkjet printing.

Implementation Method 1

a compound represented by C6F13—CH2CH2O(CH2CH2O)nH Chemical formula 1, where n represents an integer of from 1 to 40

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

the pre-processing fluid has excellent wettability to an application roller and a recording medium

Methodology Applied
Scientific EffectWettability improvement: Wetting

Implementation Method 3

a compound represented by HOR1R3C—(CH2)m—CR2R4OH Chemical formula 2, where R1 and R2 each, independently represent alkyl groups having 3 to 6 carbon atoms

Methodology Applied
Scientific EffectDefoamability enhancement: Antifoam

Implementation Method 4

a water soluble flocculant

Methodology Applied
Scientific EffectFlocculation: Flocculation

Data Source

PatentUS9321931B2Pre-processing fluid, ink set, image forming apparatus, and image forming method
Publication Date: 2016.04.26 RICOH CO LTD
  • US9321931B2 patent drawing
  • US9321931B2 patent drawing
  • US9321931B2 patent drawing

AI summary

A pre-processing fluid contains water, a water soluble organic solvent, a water soluble flocculant, a compound represented by C6F13—CH2CH2O(CH2CH2O)nH Chemical formula 1, where n represents an integer of from 1 to 40, and a compound represented by HOR1R3C—(CH2)m—CR2R4OH Chemical formula 2, where R1 and R2 each, independently represent alkyl groups having 3 to 6 carbon atoms, R3 and R4 each, independently represent methyl groups or ethyl groups, and m represents an integer of from 1 to 6.