Primed Substrate Coating Uniformity

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Solution Overview

Problem

Existing spin coating techniques face challenges in achieving uniformity and efficiency, particularly in reducing the amount of liquid used, which leads to higher costs and waste, and can result in defects and imperfections in thin film layers on semiconductor substrates.

Innovation Solution

The use of a priming material tailored to the substrate and film-forming liquid, with specific adhesion groups and a linking chain, is applied to improve the flow and coverage of the film-forming liquid during the spin coating process, reducing the volume of liquid required and minimizing defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If more liquid is used in spin coating, then better coverage is achieved, but cost and waste increase

Engineering Contradiction:
Improvefilm coverage uniformityVSAvoidliquid material volume
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

A priming material is applied to the substrate before the film-forming liquid. This intermediary layer improves the flow and coverage of the subsequent liquid material, enabling better film formation with reduced liquid volume. The priming material acts as a mediator between the substrate and the film-forming liquid, enhancing wetting and distribution properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The priming material is applied in advance to prepare the substrate surface before the actual film-forming liquid is deposited. This preliminary action modifies the substrate properties to facilitate subsequent liquid distribution, allowing for more efficient use of the film-forming liquid and reduced material waste.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If spin coating parameters are optimized for uniformity, then film quality improves, but process complexity increases

Engineering Contradiction:
Improvefilm thickness uniformityVSAvoidcoating process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention changes the chemical and physical parameters of the coating system by introducing a priming material with specific molecular structure (adhesion groups and linking chain). This parameter change fundamentally alters how the liquid material interacts with the substrate, achieving improved uniformity through material composition rather than complex process control.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in improved film coverage with reduced dry spots and imperfections, allowing for more efficient use of materials and lower disposal costs, while maintaining consistent film thickness and quality.

Implementation Method 1

The priming material includes a molecule having a first group based on an attribute of the material and a second group based on an attribute of the film-forming material. The first group is configured to have a water affinity that corresponds to a water affinity of the material, and the second group is configured to have a water affinity that corresponds to a water affinity of the film-forming material.

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

Spin coating may involve depositing a material in liquid form at the center of a substrate and spinning the substrate to drive the liquid to the edges. In this way, spin coating leverages the centrifugal tendencies of the liquid to produce a film of significantly uniform thickness.

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Data Source

PatentUS11708495B2Priming material for substrate coating
Publication Date: 2023.07.25 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11708495B2 patent drawing
  • US11708495B2 patent drawing
  • US11708495B2 patent drawing

AI summary

A coating technique and a priming material are provided. In an exemplary embodiment, the coating technique includes receiving a substrate and identifying a material of the substrate upon which a layer is to be formed. A priming material is dispensed on the material of the substrate, and a film-forming material is applied to the priming material. The priming material includes a molecule containing a first group based on an attribute of the substrate material and a second group based on an attribute of the film-forming material. Suitable attributes of the substrate material and the film-forming material include water affinity and degree of polarity and the first and second groups may be selected to have a water affinity or degree of polarity that corresponds to that of the substrate material and the film-forming material, respectively.