Printable Silicone Adhesive Composition for Low-Viscosity Inkjet Coating

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Solution Overview

Problem

Conventional curable silicone compositions for forming silicone pressure sensitive adhesives have high viscosities, making them unsuitable for inkjet printing and difficult to achieve thin layers in electronic device fabrication, and solvent-based methods cause non-uniformity and environmental concerns.

Innovation Solution

A curable silicone composition with a maximum viscosity of 100 mPa·s, comprising specific aromatic compounds, alkenyl functional polyorganosilicate resin, and a hydrosilylation reaction catalyst, allowing for inkjet printing and thin layer formation in electronic devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional curable silicone compositions with linear silicone gum and solid tackifier resin are used, then adhesive performance is achieved, but viscosity becomes too high (thousands of mPa·s or higher) for inkjet printing

Engineering Contradiction:
Improveadhesive performanceVSAvoidviscosity suitability for inkjet printing
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent changes the chemical composition parameters by replacing conventional linear silicone gum with aromatic compounds containing alkenyl groups and silicon-bonded hydrogen atoms, and replacing solid tackifier resin with alkenyl-functional polyorganosilicate resin. This parameter change reduces viscosity from thousands of mPa·s to below 100 mPa·s while maintaining adhesive performance through the reactive diluent mechanism.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces reactive diluents (alkenyl-functional polyorganosilicate resin and optionally alkenyl-functional polydiorganosiloxane) as intermediary substances that lower the viscosity of the composition. These intermediaries enable the high-viscosity conventional adhesive to be transformed into an inkjet-printable low-viscosity composition without sacrificing adhesive properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If volatile solvents are added to reduce viscosity for coating, then viscosity decreases, but solvent drying causes non-uniformity, roughness, shrinkage, and environmental problems

Engineering Contradiction:
Improveviscosity for coatingVSAvoiduniformity of printed layer
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent extracts and eliminates volatile solvents from the composition entirely, replacing them with non-volatile reactive diluents (alkenyl-functional polyorganosilicate resin). This removal of harmful volatile solvents prevents solvent drying issues such as non-uniformity, roughness, and shrinkage, while still achieving the required low viscosity for inkjet printing.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent converts the potential harm of using solvents (which cause uniformity issues and environmental problems) into a benefit by using reactive diluents that not only reduce viscosity but also participate in the curing reaction. The reactive diluents become part of the crosslinked network, ensuring uniform curing without solvent-related defects.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Length of stationary object

If conventional dispensing or lamination methods are used for adhesive application, then adhesive layers can be formed, but achieving layers with thickness≤50 μm is difficult, limiting thin electronic device fabrication

Engineering Contradiction:
Improveadhesive layer thicknessVSAvoidfabrication capability for thin devices
Core Design Contradiction:
Length of stationary objectVSEase of manufacture

Solution Approach 1:

The patent replaces conventional mechanical application methods (dispensing, lamination) with inkjet printing technology. The low viscosity of the composition (below 100 mPa·s) enables precise inkjet deposition that can form uniform adhesive layers with thickness≤50 μm, which is difficult to achieve with traditional mechanical methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables uniform and environmentally friendly inkjet printing of thin adhesive layers in electronic devices, overcoming viscosity issues and solvent-related problems.

Implementation Method 1

a curable silicone composition with viscosity ≤100 mPa·s... comprising (A) an aromatic compound having two alkenyl groups per molecule... (B) an aromatic compound having two silicon bonded hydrogen atoms per molecule... (G) a hydrosilylation reaction catalyst

Methodology Applied
Scientific EffectHydrosilylation reaction: Chemical Bonding

Data Source

PatentUS12516229B2Printable silicone composition and methods for its preparation and use
Publication Date: 2026.01.06 DOW SILICONES CORP
  • US12516229B2 patent drawing
  • US12516229B2 patent drawing
  • US12516229B2 patent drawing

AI summary

A curable silicone composition has viscosity≤100 mPa·s at 25° C. The composition is suitable for use in a printing method. The composition can cure via hydrosilylation reaction to form a silicone adhesive suitable for use in the field of (opto)electronic device fabrication.