Prism Sheet Curing Composition for Refractive Index and Abrasion Resistance

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Solution Overview

Problem

Existing prism sheets face challenges in achieving both high refractive index and good abrasion resistance due to the trade-off between flexibility and chipping resistance, particularly with materials having high refractive indices.

Innovation Solution

A prism sheet comprising a micro concave-convex structure layer formed from an active energy ray curing composition containing 40% or more inorganic nanoparticles, such as zirconia, with specific indentation depth and elastic deformation properties, and a transparent substrate layer, optimized for mechanical properties and abrasion resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If a material having a high refractive index is used, then the refractive index is improved, but the flexibility of the resin cured product decreases

Engineering Contradiction:
Improverefractive indexVSAvoidflexibility
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the resin by incorporating specific monomers (acrylonitrile, methacrylonitrile, or cyanogen bromide) in controlled amounts (0.1-10 mass%) to modify the polymerization characteristics and crosslinking density, achieving a balance between high refractive index and maintained flexibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite resin system combining multiple components: base resin, high-refractive-index particles, and specific monomer additives, where the synergistic effect of these components achieves both high refractive index and adequate flexibility that neither component could achieve alone

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If a material having a high refractive index is used, then the refractive index is improved, but the abrasion resistance deteriorates

Engineering Contradiction:
Improverefractive indexVSAvoidabrasion resistance
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent modifies the resin composition parameters by adding specific monomers that influence crosslinking density and molecular weight distribution, which directly affects abrasion resistance while maintaining the high refractive index property

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops a composite material system combining resin, high-refractive-index particles, and functional monomers where the composite structure provides both optical performance (high refractive index) and mechanical durability (abrasion resistance) through the synergistic interaction of components

Inventive Principle:
Principle #40Composite materials

3Illumination intensity

If the convex shape is made sharp to improve optical function, then the optical performance is improved, but the chipping due to friction increases

Engineering Contradiction:
Improveoptical functionVSAvoidchipping resistance
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The patent changes the material parameters (resin composition, crosslinking density, molecular weight) to optimize the mechanical strength of the convex portions, allowing sharp geometric shapes to maintain structural integrity and resist chipping during handling and operation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves both high refractive index and excellent abrasion resistance by ensuring a minimum indentation depth and elastic deformation power, enhancing the sheet's durability and flexibility.

Implementation Method 1

a material having a high refractive index or adding organic or inorganic high-refractive-index fine particles has been proposed

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

a micro concave-convex structure layer which is a cured product of an active energy ray curing composition

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS20250224545A1Prism sheet and active energy ray curing composition for prism sheet
Publication Date: 2025.07.10 DIC CORP
  • US20250224545A1 patent drawing
  • US20250224545A1 patent drawing
  • US20250224545A1 patent drawing

AI summary

According to the present invention, both good abrasion resistance and a high refractive index can be achieved with a material having a certain parameter, as evaluated using a flat indenter to evaluate mechanical properties of a convex portion of a prism sheet. The prism sheet of the present invention includes a micro concave-convex structure layer which is a cured product of an active energy ray curing composition containing 40 mass % or more of inorganic nanoparticles, and a transparent substrate layer. The micro concave-convex structure layer has a micro concave-convex structure with a period of 20 μm to 100 μm on a surface thereof. The micro concave-convex structure layer has an indentation depth (hmax) of 8 μm or more at a maximum test force and an elastic deformation power (nIT) of 50% or more.