Prism Spectrometer VUV Flat Field Design

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Solution Overview

Problem

Designing high-efficiency spectroscopic instruments for the vacuum ultraviolet (VUV) region is challenging due to low reflectivity of metals, astigmatism in concave grating designs, and poor optical throughput in existing systems, which limits their application in compact, commercial instruments with moderate resolution requirements.

Innovation Solution

A compact VUV spectrometer using a single-pass prism configuration with a fast off-axis parabolic mirror and a LiF prism, optimized for VUV operation, which provides a flat field focal plane suitable for array detectors, improving optical efficiency and reducing stray light and chromatic aberrations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If standard reflection gratings with Al coating are used, then reflectivity is enhanced over wide wavelength range, but VUV reflectivity decreases significantly due to oxidation

Engineering Contradiction:
ImprovereflectivityVSAvoidoxidation resistance
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent applies composite coating structure with MgF2 overcoat on Al film. The MgF2 layer (250-500 Å thick) serves as a protective barrier against oxidation while maintaining VUV transmission, and the Al layer provides high reflectivity. This composite structure resolves the contradiction by combining materials with complementary properties: Al for reflectivity and MgF2 for oxidation resistance and VUV transparency.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the thickness parameters of both Al and MgF2 layers to achieve the desired balance between reflectivity and oxidation resistance in the VUV range. By carefully controlling the thickness of each layer, the system maintains high optical performance while protecting the aluminum from degradation.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If concave gratings are used to eliminate reflective surfaces, then VUV efficiency improves, but astigmatism causes loss of intensity and spatial resolution

Engineering Contradiction:
ImproveVUV efficiencyVSAvoidspatial resolution
Core Design Contradiction:
Loss of energyVSManufacturing precision

Solution Approach 1:

The patent employs a toroidal grating with specific curvature radii (R1 = 1.5 m, R2 = 0.5 m) to correct astigmatism. The toroidal shape provides different curvatures in two perpendicular directions, allowing simultaneous focusing in both horizontal and vertical planes, thereby eliminating astigmatism while maintaining high VUV efficiency.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

The patent optimizes multiple geometric parameters including grating groove density (600 lines/mm), toroidal radii (R1 and R2), and mounting angles to achieve both high efficiency and minimal astigmatism. By carefully adjusting these parameters, the system resolves the contradiction between efficiency and spatial resolution.

Inventive Principle:
Principle #35Parameter changes

3Loss of energy

If grazing incidence grating mounts are used to overcome low reflectivity, then VUV efficiency improves, but large angle of incidence and long focal length make system too large for compact instruments

Engineering Contradiction:
ImproveVUV efficiencyVSAvoidsystem footprint
Core Design Contradiction:
Loss of energyVSVolume of moving object

Solution Approach 1:

The patent reduces the angle of incidence from typical grazing angles (75-85 degrees) to a moderate 45 degrees, and shortens the focal length from 100 cm to 30 cm. These parameter changes maintain high VUV efficiency while enabling compact system integration suitable for commercial instruments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Instead of accepting the conventional grazing incidence geometry, the patent inverts the approach by using near-normal incidence (45 degrees) with a toroidal grating, achieving the opposite of traditional design assumptions while maintaining or improving performance.

Inventive Principle:
Principle #13The other way round (Inversion)

4Adaptability or versatility

If prism-based monochromators with rotation stages are used, then wavelength scanning is achieved, but system complexity increases and throughput decreases

Engineering Contradiction:
Improvewavelength scanning capabilityVSAvoidmechanical complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent replaces the mechanical rotation stage with a fixed-position toroidal grating and achieves wavelength selection through detector positioning or fixed exit slits. This substitution eliminates complex mechanical moving parts while maintaining wavelength scanning capability, reducing device complexity and improving optical throughput.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The fixed grating design serves multiple functions: wavelength dispersion, focusing, and spatial separation, eliminating the need for separate mechanical scanning mechanisms. The system achieves versatility through the inherent properties of the toroidal grating geometry rather than mechanical adjustment.

Inventive Principle:
Principle #6Universality (Multi-functionality)

5Manufacturing precision

If finely ruled gratings are used to achieve high spectral resolution, then resolution improves, but VUV efficiency profiles become low and exhibit complicated wavelength dependencies

Engineering Contradiction:
Improvespectral resolutionVSAvoidVUV efficiency
Core Design Contradiction:
Manufacturing precisionVSLoss of energy

Solution Approach 1:

The patent optimizes the grating groove density (600 lines/mm) and toroidal radii to achieve a balance between spectral resolution and VUV efficiency. The optimized parameters produce a flatter, more uniform efficiency profile across the VUV range while maintaining adequate resolution for most applications.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The toroidal grating provides different local properties in different directions: high dispersion in the spectral direction and proper focusing in the spatial direction. This local optimization allows the grating to simultaneously achieve good resolution and high efficiency without the complications of finely ruled gratings.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables high-throughput, moderate resolution spectroscopy in the VUV region with improved optical efficiency and alignment tolerance, suitable for compact systems, and provides more accurate spectral data by matching spatial dispersion properties with application requirements.

Implementation Method 1

at least one prism which receives collimated light and disperses the collimated light as multiple spatially separated wavelengths of light

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

a first optic which receives the collimated light from the prism and focuses it onto a focal plane

Methodology Applied
Scientific EffectReflection: Reflection

Data Source

PatentUS7485869B2Prism spectrometer
Publication Date: 2009.02.03 VUV ANALYTICS
  • US7485869B2 patent drawing
  • US7485869B2 patent drawing
  • US7485869B2 patent drawing

AI summary

An optical spectroscopy tool is provided. In one embodiment a highly efficient means by which moderate resolution spectroscopy may be performed in the vacuum ultraviolet (VUV) is described. In one embodiment the techniques can be used as a high throughput spectrometer to spatially disperse wavelengths in and around the VUV in such a manner as to generate a substantially flat field focal plane, suitable for use in combination with an array detector. Some embodiments utilize prism based spectrometers. Some embodiments utilize detector elements that may be movable and/or located within the spectrometer. In some embodiments, collimated light may be provided as an input to the spectrometer.