Process Gas Monitoring for Decomposition Product Control

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Solution Overview

Problem

The semiconductor manufacturing industry faces challenges in efficiently and sustainably depositing thin films like silicon nitride (SiN) using plasma-enhanced processes, which require monitoring and controlling the concentration of thermally decomposable chemical substances to prevent degradation and optimize process efficiency.

Innovation Solution

A process gas monitoring apparatus and method that includes a gas analyzer to measure the concentration of decomposition products, a control unit to generate signals based on predetermined thresholds, and a volatilization vessel to manage the supply of chemical substances, ensuring safe and efficient operation of substrate processing apparatuses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If plasma-enhanced processes are used to deposit thin films at low temperatures and high deposition rates, then deposition efficiency is improved, but monitoring and controlling the concentration of thermally decomposable chemical substances becomes more difficult to prevent degradation

Engineering Contradiction:
Improvedeposition rateVSAvoidprocess gas quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The gas analyzer monitors the concentration of decomposition products in the process gas before it enters the reaction chamber. When the concentration exceeds a predetermined threshold, the system preemptively generates a control signal to replace the process gas, preventing degradation that would affect deposition quality. This preliminary detection and action resolve the contradiction by maintaining reliability without sacrificing deposition efficiency.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system implements a feedback mechanism where the gas analyzer continuously measures decomposition product concentration and feeds this information to the control unit. The control unit adjusts the process gas supply based on real-time concentration data, ensuring that deposition proceeds with high-quality gas throughout the process. This closed-loop feedback maintains both high deposition rates and process gas quality.

Inventive Principle:
Principle #23Feedback

2Reliability

If continuous monitoring of decomposition product concentration is implemented, then process gas quality is maintained, but device complexity increases

Engineering Contradiction:
Improveprocess gas qualityVSAvoidmonitoring system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The monitoring function is extracted as a separate, dedicated gas analyzer component rather than being integrated into the main deposition system. This modular extraction allows for specialized monitoring capability while keeping the overall system architecture simple and manageable. The control unit then processes only the essential concentration data from the analyzer, maintaining reliability without excessive complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If process gas is replaced when decomposition product concentration exceeds threshold, then deposition precision is maintained, but loss of time occurs during gas replacement

Engineering Contradiction:
Improvedeposition qualityVSAvoidgas replacement time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The system continuously monitors decomposition product concentration and detects threshold exceedance before it significantly impacts deposition quality. By acting at the precise moment when concentration reaches the threshold, the system minimizes the time the degraded gas is present in the system, thereby reducing gas replacement time while maintaining deposition precision.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The gas replacement process is designed to occur as quickly as possible, and the system is configured to minimize interruption to the deposition process. The control unit manages the replacement operation to maintain continuous deposition action, reducing the effective time loss while ensuring deposition quality is preserved through timely gas replacement.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances precision and accuracy in monitoring process gas degradation, optimizing chemical substance utilization, and reducing waste by automatically controlling the supply of thermally decomposable chemicals, thereby improving deposition efficiency and sustainability in semiconductor manufacturing.

Implementation Method 1

a gas analyzer configured to generate a concentration signal indicative of concentration of the decomposition product in the process gas

Methodology Applied
Scientific EffectGas analysis: Absorption Spectroscopy

Implementation Method 2

a chemical substance thermally decomposable to form a decomposition product

Methodology Applied
Scientific EffectThermal decomposition: Thermolysis

Data Source

PatentUS20260005040A1Process gas monitoring apparatus, volatilization vessel, substrate processing apparatus, and method
Publication Date: 2026.01.01 ASM IP HLDG BV
  • US20260005040A1 patent drawing
  • US20260005040A1 patent drawing
  • US20260005040A1 patent drawing

AI summary

This disclosure relates to a process gas monitoring apparatus, a volatilization vessel, a substrate processing apparatus, and a method for monitoring supply of process gas into a process chamber. The process gas comprises a chemical substance thermally decomposable to form a decomposition product, and the method comprises measuring concentration of the decomposition product in the process gas.