Prohexadione Calcium Granulate with Solid Acidifier

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Solution Overview

Problem

Existing formulations of carboxy-containing growth regulators like prohexadione salts require complex preparation, involve handling irritant citric acid, and are prone to errors, making them difficult and time-consuming for farmers to use, especially when mixed with hard water.

Innovation Solution

A granulate comprising prohexadione calcium and a solid acidulant, such as hydrogen sulfate or hydrogen phosphate, which is easy to handle, storage-stable, and can maintain high biological effectiveness even when diluted with hard water, produced using extrusion or fluidized bed granulation processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If citric acid is added to adjust pH and improve solubility, then absorption of active ingredient is faster, but preparation complexity increases and handling safety deteriorates

Engineering Contradiction:
Improveabsorption speedVSAvoidpreparation complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent combines the growth regulator (prohexadione calcium) with the acidulant (citric acid) into a single pre-formulated granulate product. This merging eliminates the need for farmers to separately handle and mix citric acid with the growth regulator, thereby reducing preparation complexity and handling safety risks while maintaining the fast absorption benefit through the pre-acidified formulation.

Inventive Principle:
Principle #5Merging (Combining)

2Quantity of substance

If citric acid is added to adjust pH, then solubility in water improves, but storage space requirements and handling safety deteriorate

Engineering Contradiction:
ImprovesolubilityVSAvoidhandling safety
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent merges the growth regulator and acidulant into a single pre-formulated granulate, eliminating the need for farmers to separately store and handle citric acid. The acidulant is already incorporated at the appropriate concentration to ensure good solubility while removing the safety hazards associated with handling pure citric acid during application.

Inventive Principle:
Principle #5Merging (Combining)

3Adaptability or versatility

If multiple separate components are used, then formulation flexibility is maintained, but preparation time and error rate increase

Engineering Contradiction:
Improveformulation flexibilityVSAvoidpreparation time
Core Design Contradiction:
Adaptability or versatilityVSLoss of time

Solution Approach 1:

The patent applies preliminary action by pre-formulating the growth regulator with the acidulant and other necessary components into a complete granulate product before delivery to the farmer. This preliminary formulation eliminates the need for farmers to perform complex mixing operations at the time of application, significantly reducing preparation time and minimizing errors while maintaining the flexibility to adjust application rates based on crop needs.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The granulate simplifies the preparation process, eliminates the need for additional acidulants, and ensures quick dispersion in water, enhancing the absorption and efficiency of the active ingredient, particularly under unfavorable application conditions.

Implementation Method 1

The granules are very stable in storage and can be diluted with hard water without homogenization. The granules advantageously disperse quickly and completely in water.

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

The spray mixture is usually prepared by adding water (e.g. tap water or well water) to the prohexadione salt in the spray tank and then setting a slightly acidic pH value by adding citric acid.

Methodology Applied
Scientific EffectAcidification:

Data Source

PatentEP2458982B1Granulate containing a carboxylic growth regulator and a solid acidifier
Publication Date: 2014.06.25 BASF SE
  • EP2458982B1 patent drawing
  • EP2458982B1 patent drawing
  • EP2458982B1 patent drawing

AI summary

The present invention relates to a granulate comprising a carboxylic growth regulator and a solid acidifier. The invention further relates to a method for producing the granulate by extrusion or fluidized bed granulation. The invention further relates to a use of the granulate for producing an aqueous spray mixture, in which the granulate is brought into contact with water, and the use of the granulate for regulating the growth of plants.